Evaluating redox cycling across the Toarcian Oceanic Anoxic Event with implications for paleo-environmental reconstructions and organic matter sulfurization
| dc.contributor.author | Marroquin, Selva Mariana | en |
| dc.contributor.committeechair | Gill, Benjamin C. | en |
| dc.contributor.committeemember | Xiao, Shuhai | en |
| dc.contributor.committeemember | Romans, Brian W. | en |
| dc.contributor.committeemember | Caruthers, Andrew H. | en |
| dc.contributor.committeemember | Eriksson, Kenneth A. | en |
| dc.contributor.committeemember | Nesbitt, Sterling James | en |
| dc.contributor.department | Geosciences | en |
| dc.date.accessioned | 2022-06-03T06:00:12Z | en |
| dc.date.available | 2022-06-03T06:00:12Z | en |
| dc.date.issued | 2020-12-09 | en |
| dc.description.abstract | Understanding oxygenation throughout Earth history, particularly intervals where marine deoxygenation occurred, are crucial to investigating the changes in habitability on Earth. Marine deoxygenation events, in particular, can result in changes in the carbon, sulfur, and iron cycles on our planet. Changes in these elemental cycles lead to distinctive variation in the chemical composition of seawater that is recorded in marine sediments that are preserved into the sedimentary record. Our modern ocean is experiencing rapid deoxygenation, thus understanding the duration and extent of ancient deoxygenation events is vital to predicting future climate scenarios. Here I investigated the record of environmental change during the Early Jurassic Toarcian Oceanic Anoxic Event or T-OAE (~183 Ma). The first chapter of this dissertation investigates the record of marine anoxia across the Pliensbachian to Toarcian transition. Specifically, I investigate the temporal and geographic development of anoxia across three basins from the European Epicontinental Seaway. Through utilization of iron speciation, a local redox proxy, I identify anoxia developing before and persisting well after the negative carbon isotope excursion (NCIE) conventionally used to define the T-OAE. These data indicate an increase in the occurrence of anoxia at the Pliensbachian – Toarcian boundary, coincident with the initial phase of volcanism associated with the Karoo-Ferrar Large Igneous Province and an interval of heightened marine invertebrate extinction. Ultimately, our data support a greater temporal extent of anoxic conditions around the T-OAE, which support the greater sensitivity of marine oxygen levels to climatic change outside of the NCIE interval. The second chapter of this dissertation assesses the occurrence and extent of organic matter sulfurization (OMS), a biogeochemical feedback known to enhance the preservation and burial of OM. Because this process is accelerated when euxinic conditions develop in the water column, I investigated it as a mechanism promoting OM burial across two oceanic anoxic events of the Mesozoic. Importantly, I find that sulfurization does not occur uniformly across both events and propose a conceptual model of the depositional settings most favorable for sulfurization to occur and when throughout geologic time OMS is most likely to influence the global cycles of carbon and sulfur. | en |
| dc.description.abstractgeneral | Understanding past time intervals where there was widespread loss of oxygen in the oceans is crucial to understanding habitability on Earth. Since our modern oceans are experiencing a rapid loss of oxygen, understanding the duration and extent of ancient marine oxygen loss events is vital to predicting future habitability of the oceans. These ancient events can result in distinctive changes in the carbon, sulfur, and iron cycles on our planet. Variation in these elemental cycles lead to distinctive shifts in the chemical composition of seawater that is recorded in marine sediments that get preserved as rocks in the geologic record. Here, I investigated the record of environmental change during the Early Jurassic Toarcian Oceanic Anoxic Event or T-OAE (~183 Ma). The first chapter of this dissertation investigates the record of marine oxygen loss across the T-OAE. Specifically, I investigate the temporal and geographic development of oxygen loss across three ancient marine basins. Through utilization of a local tracer of water column oxygen loss (e.g. iron speciation) I identify oxygen loss developing before and persisting well after the conventional timeframe associated with the event. These data indicate oxygen loss first occurred before the T-OAE, coincident with the initial phase of volcanic eruptions from the Karoo-Ferrar Large Igneous Province and an interval of heightened marine extinction. Ultimately, these data support a longer time interval of oxygen loss around the T-OAE and the greater sensitivity of marine oxygen levels to climatic change. The second chapter of this dissertation assesses the occurrence and extent of organic matter sulfurization (OMS), a feedback known to enhance the preservation and burial of organic matter (OM). Because this process is accelerated when oxygen is lost and free sulfur builds up in the water column, I investigated its occurrence across two oceanic oxygen loss events of the Mesozoic Era. Importantly, I find that sulfurization does not occur uniformly across both events and propose a conceptual model of the settings most favorable for sulfurization to occur and also when in geologic time it is most likely to influence the global cycling of carbon and sulfur. | en |
| dc.description.degree | Doctor of Philosophy | en |
| dc.format.medium | ETD | en |
| dc.identifier.other | vt_gsexam:28061 | en |
| dc.identifier.uri | http://hdl.handle.net/10919/110407 | en |
| dc.publisher | Virginia Tech | en |
| dc.rights | In Copyright | en |
| dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | en |
| dc.subject | Ancient marine redox | en |
| dc.subject | oceanic anoxic event | en |
| dc.subject | Toarcian | en |
| dc.subject | sedimentary geochemistry | en |
| dc.subject | sulfurization | en |
| dc.title | Evaluating redox cycling across the Toarcian Oceanic Anoxic Event with implications for paleo-environmental reconstructions and organic matter sulfurization | en |
| dc.type | Dissertation | en |
| thesis.degree.discipline | Geosciences | en |
| thesis.degree.grantor | Virginia Polytechnic Institute and State University | en |
| thesis.degree.level | doctoral | en |
| thesis.degree.name | Doctor of Philosophy | en |
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