Nucleobase-Functionalized ABC Triblock Copolymers: Self-assembly of Supramolecular Architectures

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Date

2014-06-24

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Publisher

The Royal Society of Chemistry

Abstract

RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-Tg soft central block. ABC triblock copolymers self-assembled into well-defined lamellar microphase-separated morphologies for potential applications as thermoplastic elastomers. Complementary hydrogen bonding within the hard phase facilitated self-assembly and enhanced mechanical performance.

Description

Keywords

Reversible addition-fragmentation chain polymerization, Polymer self-assembly

Citation

Zhang, K., Fahs, G. B., Aiba, M., Moore, R. B., & Long, T. E. (2014). Nucleobase-functionalized ABC triblock copolymers: self-assembly of supramolecular architectures. Chemical Communications, 50(65), 9145-9148. doi: 10.1039/C4CC03363A

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http://hdl.handle.net/10919/51698

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Scholarly Works, Chemistry
Strategic Growth Area: Economical and Sustainable Materials (ESM)