Structural studies of precursor and partially oxidized conducting complexes. II. A neutron diffraction study of disodium dibromotetracyanoplatinate dihydrate
| dc.contributor.author | Maffly, Robert L. | en |
| dc.contributor.author | Johnson, Paul L. | en |
| dc.contributor.author | Koch, Timothy R. | en |
| dc.contributor.author | Williams, Jack M. | en |
| dc.date.accessioned | 2022-08-17T19:47:15Z | en |
| dc.date.available | 2022-08-17T19:47:15Z | en |
| dc.date.issued | 1977-02-01 | en |
| dc.date.updated | 2022-08-06T22:26:45Z | en |
| dc.description.abstract | Na<sub>2</sub>[Pt(CN)<sub>4</sub>Br<sub>2</sub>]. 2H<sub>2</sub>O, orthorhombic, Pnma (D<sub>2h</sub><sup>16</sup>), a = 11.949(11), b = 15.124(14), c = 6.487 (6) Å, Z = 4, D<sub>m</sub> = 3.06, D<sub>x</sub> = 3.065 g cm<sup>-3</sup>. A room-temperature, single-crystal neutron diffraction study was performed. The structure was solved by direct methods and refined by full-matrix least-squares techniques to R(F<sub>0</sub><sup>2</sup>) = 0.068 for 1447 observed reflections > 1σ(F<sub>0</sub><sup>2</sup>). The structure consists of octahedrally coordinated platinum (IV) complex anions interacting with both the sodium cations and the waters of hydration. | en |
| dc.description.version | Published version | en |
| dc.format.extent | Pages 558-560 | en |
| dc.format.mimetype | application/pdf | en |
| dc.identifier.doi | https://doi.org/10.1107/s0567740877004075 | en |
| dc.identifier.issn | 0567-7408 | en |
| dc.identifier.issue | 2 | en |
| dc.identifier.orcid | Koch, Timothy [0000-0002-8026-9653] | en |
| dc.identifier.uri | http://hdl.handle.net/10919/111542 | en |
| dc.identifier.volume | 33 | en |
| dc.language.iso | en | en |
| dc.publisher | International Union of Crystallography | en |
| dc.rights | Public Domain (U.S.) | en |
| dc.rights.uri | http://creativecommons.org/publicdomain/mark/1.0/ | en |
| dc.title | Structural studies of precursor and partially oxidized conducting complexes. II. A neutron diffraction study of disodium dibromotetracyanoplatinate dihydrate | en |
| dc.title.serial | Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry | en |
| dc.type | Article - Refereed | en |
| dc.type.dcmitype | Text | en |
| pubs.organisational-group | /Virginia Tech | en |
| pubs.organisational-group | /Virginia Tech/VT Carilion School of Medicine | en |
| pubs.organisational-group | /Virginia Tech/VT Carilion School of Medicine/Internal Medicine | en |
| pubs.organisational-group | /Virginia Tech/VT Carilion School of Medicine/Internal Medicine/General IM | en |
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