Synthesis, characterization, and luminescent properties of two new Zr(IV) metal-organic frameworks based on anthracene derivatives

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dc.contributor.authorRowe, Jennifer M.en
dc.contributor.authorSoderstrom, Erin M.en
dc.contributor.authorZhu, Jieen
dc.contributor.authorUsov, Pavel M.en
dc.contributor.authorMorris, Amanda J.en
dc.contributor.departmentChemistryen
dc.contributor.departmentMacromolecules Innovation Instituteen
dc.date.accessioned2019-09-04T13:34:27Zen
dc.date.available2019-09-04T13:34:27Zen
dc.date.issued2018-09en
dc.description.abstractMetal-organic frameworks (MOFs) are crystalline materials constructed from metal ions or clusters, connected by multidentate organic ligands. Herein, we describe the synthesis and photophysical properties of two Zr-based, anthracene-containing MOFs, assembled from 2,6-anthracenedicarboxylic acid (2,6-ADCA and 2,6-MOF) and 1,4-anthracenedicarboxylic acid (1,4-ADCA and 1,4-MOF). The 2,6-ADCA analogue formed a highly crystalline octahedral structure that is isostructural with the well-known UiO-67 frameworks. Incorporation of the 1,4-ADCA ligand, on the other hand, resulted in large rod-shaped crystals. Both MOFs exhibit linker-based luminescence. The excited-state properties of the 2,6-MOF and 1,4-MOF were examined using stead-state diffuse reflectance and emission spectroscopies and time-correlated single photon counting (TCSPC) spectroscopy. The photophysical properties of the MOFs are compared with those of the corresponding ligand in solution.en
dc.description.notesThis material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Award Number DE-SC0012446.en
dc.description.sponsorshipU.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0012446]en
dc.format.mimetypeapplication/pdfen
dc.identifier.doihttps://doi.org/10.1139/cjc-2017-0445en
dc.identifier.eissn1480-3291en
dc.identifier.issn0008-4042en
dc.identifier.issue9en
dc.identifier.urihttp://hdl.handle.net/10919/93349en
dc.identifier.volume96en
dc.language.isoenen
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectreseau metallo-organiqueen
dc.subjectanthraceneen
dc.subjectluminescenceen
dc.subjectphotophysiqueen
dc.titleSynthesis, characterization, and luminescent properties of two new Zr(IV) metal-organic frameworks based on anthracene derivativesen
dc.title.serialCanadian Journal of Chemistryen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
dc.type.dcmitypeStillImageen

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