Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers

dc.contributor.authorZhang, Kerenen
dc.contributor.authorTalley, Samantha J.en
dc.contributor.authorYu, Ya Pengen
dc.contributor.authorMoore, Robert Bowenen
dc.contributor.authorMurayama, Mitsuhiroen
dc.contributor.authorLong, Timothy E.en
dc.contributor.departmentChemistryen
dc.contributor.departmentMacromolecules Innovation Instituteen
dc.contributor.departmentMaterials Science and Engineeringen
dc.date.accessioned2017-05-01T06:42:16Zen
dc.date.available2017-05-01T06:42:16Zen
dc.date.issued2016-05-11en
dc.description.abstractABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates. Intermolecular hydrogen bonding formed thymine–adenine triplets and promoted self-assembly into well-defined lamellae consisting of poly(n-butyl acrylate) soft domains and complementary nucleobase hard domains, while thymine–adenine duplets contributed to superior mechanical properties.en
dc.format.extent7564-7567en
dc.format.mimetypeapplication/pdfen
dc.identifierc6cc03502g.pdfen
dc.identifierc6cc03502g1.pdfen
dc.identifier.doihttps://doi.org/10.1039/c6cc03502gen
dc.identifier.eissn1364-548Xen
dc.identifier.issn1359-7345en
dc.identifier.issue48en
dc.identifier.urihttp://hdl.handle.net/10919/77548en
dc.identifier.volume52en
dc.language.isoen_USen
dc.publisherRoyal Society of Chemistryen
dc.relation.ispartofRoyal Society of Chemistry Gold Open Access - 2016en
dc.rightsCreative Commons Attribution-NonCommercial 3.0 Unporteden
dc.rights.holderZhang, Kerenen
dc.rights.holderTalley, Samantha J.en
dc.rights.holderYu, Ya Pengen
dc.rights.holderMoore, Robert B.en
dc.rights.holderMurayama, Mitsuhiroen
dc.rights.holderLong, Timothy E.en
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/en
dc.titleInfluence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymersen
dc.title.serialChemical Communicationsen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
dc.type.dcmitypeDataseten
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