Absolute coverage measurements of ultrathin alkali-metal films on reconstructed silicon

dc.contributor.authorBanerjee, Rajarshien
dc.contributor.departmentPhysicsen
dc.date.accessioned2016-06-27T19:03:18Zen
dc.date.available2016-06-27T19:03:18Zen
dc.date.issued2001en
dc.description.abstractMetal/semiconductor interfaces, particularly those involving Si, are of great technological and scientific interest. In atomically abrupt interfaces, many properties are determined by interatomic interactions over a few layers, i.e., over ~1 nanometer. The initial stages of growth of an atomic layer related to structural and electronic properties are thus important to thin film behavior. Surface science studies on metal-semiconductor systems often lead to contradictory conclusions regarding bonding sites and even whether the first layer is metallic or not. A key piece of information that must be consistent with any study is the number of atoms per unit area in the first layer, which is difficult to assess directly. Alkali-metal-semiconductor systems have been studied as model abrupt interfaces for several years. Novel effects, such as electron localization, were observed. Still, determinations of absolute coverage have been lacking. This dissertation describes results of absolute coverage measurements for Cs on Si(100)(2X1), Si(111)(7X7), and Si (111)(v3 X v3)R30°-B reconstructed surfaces using Rutherford Backscattering Spectrometry in ultrahigh vacuum. The results bracket possible structural models for these systems. For the Cs/Si(111)(v3 X v3)R30°-B interface, this work confirms conclusions regarding electron localization effects and introduces considerations of ion-beam-induced desorption for the weakly-bound Csen
dc.format.mimetypeapplication/pdfen
dc.identifiereprint:260en
dc.identifier.urihttp://hdl.handle.net/10919/71500en
dc.language.isoenen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjectreconstructionen
dc.subjectsiliconen
dc.subjectthin filmsen
dc.subjectRBSen
dc.subjectinterfaceen
dc.subjectsurface physicsen
dc.subjectalkali metalsen
dc.subjectcesiumen
dc.subjectordereden
dc.subjectordered growthen
dc.subjectepitaxyen
dc.subjection scatteringen
dc.subjectsemiconductorsen
dc.subjectmetalizationen
dc.subjectcharacterizationen
dc.subjectRutherforden
dc.subjectboronateden
dc.subjectdopeden
dc.subject.lccQCen
dc.titleAbsolute coverage measurements of ultrathin alkali-metal films on reconstructed siliconen
dc.typeDissertationen
thesis.degree.grantorDrexel Universityen
thesis.degree.leveldoctoralen

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