The Sʀɴ1 reactivity of selected aromatic diazines

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dc.contributor.authorCarver, David Reginalden
dc.contributor.committeechairWolfe, James F.en
dc.contributor.committeememberHudlicky, M.en
dc.contributor.committeememberBell, Harold M.en
dc.contributor.committeememberTaylor, Larry T.en
dc.contributor.committeememberSanzone, Georgeen
dc.contributor.departmentChemistryen
dc.date.accessioned2014-03-14T21:23:16Zen
dc.date.adate2012-11-30en
dc.date.available2014-03-14T21:23:16Zen
dc.date.issued1979-08-05en
dc.date.rdate2012-11-30en
dc.date.sdate2012-11-30en
dc.description.abstractThe scope and limitations of aromatic diazines undergoing nucleophilic substitution reactions occurring via a radical-chain Sʀɴ1 mechanism were investigated. The study was conducted on a series of mono- and dihalogenated aromatic diazines interacting with various ketone enolates in ammonia. Results indicate that this previously unrecognized reaction pathway in these nitrogen heterocycles is easily obtained and should prove of great synthetic utility in preparation of substituted diazines.en
dc.description.degreePh. D.en
dc.format.extentv, 160 leavesen
dc.format.mediumBTDen
dc.format.mimetypeapplication/pdfen
dc.identifier.otheretd-11302012-040014en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-11302012-040014/en
dc.identifier.urihttp://hdl.handle.net/10919/40381en
dc.language.isoenen
dc.publisherVirginia Techen
dc.relation.haspartLD5655.V856_1979.C379.pdfen
dc.relation.isformatofOCLC# 06169901en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V856 1979.C379en
dc.subject.lcshAromatic compounds -- Reactivityen
dc.subject.lcshSubstitution reactionsen
dc.titleThe Sʀɴ1 reactivity of selected aromatic diazinesen
dc.typeDissertationen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemistryen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.leveldoctoralen
thesis.degree.namePh. D.en

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