Terminology for chain polymerization (IUPAC Recommendations 2021)

dc.contributor.authorFellows, Christopher M.en
dc.contributor.authorJones, Richard G.en
dc.contributor.authorKeddie, Daniel J.en
dc.contributor.authorLuscombe, Christine K.en
dc.contributor.authorMatson, John B.en
dc.contributor.authorMatyjaszewski, Krzysztofen
dc.contributor.authorMerna, Janen
dc.contributor.authorMoad, Graemeen
dc.contributor.authorNakano, Tamakien
dc.contributor.authorPenczek, Stanislawen
dc.contributor.authorRussell, Gregory T.en
dc.contributor.authorTopham, Paul D.en
dc.date.accessioned2023-04-27T12:45:01Zen
dc.date.available2023-04-27T12:45:01Zen
dc.date.issued2022-09en
dc.description.abstractChain polymerizations are defined as chain reactions where the propagation steps occur by reaction between monomer(s) and active site(s) on the polymer chains with regeneration of the active site(s) at each step. Many forms of chain polymerization can be distinguished according to the mechanism of the propagation step (e.g., cyclopolymerization - when rings are formed, condensative chain polymerization - when propagation is a condensation reaction, group-transfer polymerization, polyinsertion, ring-opening polymerization - when rings are opened), whether they involve a termination step or not (e.g., living polymerization - when termination is absent, reversible-deactivation polymerization), whether a transfer step is involved (e.g., degenerative-transfer polymerization), and the type of chain carrier or active site (e.g., radical, ion, electrophile, nucleophile, coordination complex). The objective of this document is to provide a language for describing chain polymerizations that is both readily understandable and self-consistent, and which covers recent developments in this rapidly evolving field.en
dc.description.notesThis work was prepared under project 2010-007-1-400 of IUPAC (Funder ID: 10.13039/100006987).en
dc.description.sponsorshipIUPAC [2010-007-1-400]en
dc.description.versionPublished versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.doihttps://doi.org/10.1515/pac-2020-1211en
dc.identifier.eissn1365-3075en
dc.identifier.issue9en
dc.identifier.urihttp://hdl.handle.net/10919/114813en
dc.identifier.volume94en
dc.language.isoenen
dc.publisherWalter De Gruyteren
dc.rightsCreative Commons Attribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subjectanionicen
dc.subjectcatalyst-transferen
dc.subjectcationicen
dc.subjectchain polymerizationen
dc.subjectcontrolled polymerizationen
dc.subjectcoordinationen
dc.subjectcoordination polymerizationen
dc.subjectgroup transfer polymerizationen
dc.subjectinsertion polymerizationen
dc.subjectionic polymerizationen
dc.subjectliving polymerizationen
dc.subjectradicalen
dc.subjectradical polymerizationen
dc.subjectreverible deactivation polymerizationen
dc.titleTerminology for chain polymerization (IUPAC Recommendations 2021)en
dc.title.serialPure and Applied Chemistryen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
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