A numerical and experimental investigation of the effects of thermal history on the structure/property relationship of PPS/carbon fiber composites

dc.contributor.authorKelly, JoEllenen
dc.contributor.committeechairBaird, Donald G.en
dc.contributor.committeememberCox, David F.en
dc.contributor.committeememberDavis, Richey M.en
dc.contributor.committeememberLoos, Alfred C.en
dc.contributor.committeememberWilkes, Garth L.en
dc.contributor.departmentChemical Engineeringen
dc.date.accessioned2014-03-14T21:20:53Zen
dc.date.adate2005-10-12en
dc.date.available2014-03-14T21:20:53Zen
dc.date.issued1991-12-03en
dc.date.rdate2005-10-12en
dc.date.sdate2005-10-12en
dc.description.abstractThe purpose of this investigation was to examine the effects of thermal history during cooling from the melt on the degree of crystallinity, morphology, and mechanical properties of (polyphenylenesulfide) PPS/carbon fiber composites. Three thermal treatments were employed in this study: isothermal crystallization from the melt at 140,160,180,200, and 220°C, quenching from 315° C and then annealing at 160 and 200° C, and nonisothennal crystallization from the melt at rates varying from 0040 C/minute to 68° C/second. The effect of varying the thermal history of the sample on the degree of crystallinity developed in the matrix polymer was determined using differential scanning calorimetry. The effect of thermal history on and the resulting matrix morphology was examined by scanning electron microscopy. The subsequent effects of the degree of crystallinity and the morphology on the mechanical behavior of the samples were monitored by transverse tensile tests and flexural tests. In all cases, the transverse tensile and flexural moduli increased as the amount of crystallinity in the samples increased. However, samples with greater amounts of crystallinity did not always yield higher transverse tensile or flexural strengths. Upon examination of the composite samples by electron microscopy, it was observed that trends in the values of the transverse tensile and flexural strengths could be correlated with structural changes in the matrix. This paper is concerned with the simulation of the development of crystallinity and morphology (both amount of crystallinity and the size of spherulites) which arise during the cooling of a slab of a semicrystalline polymer reinforced with long continuous carbon fibers. This situation is commonly found during the processing of semicrystalline thermoplastic composites. Whereas published attempts at simulating this process have treated the composite material as a continuum and thereby used mass averaged physical properties (such as thermal conductivity, density, and specific heat), we use a quasi-continuum approach in which locally we consider the properties of the matrix and fiber separately. Once a temperature distribution is calculated using the continuum approach, the fmite element method is applied locally at various points in the slab to calculate the amount of crystallinity and the size of the developing spherulites. This is done by using the Avrami equation and the Hoffman and Lauritzen radial growth equation. The amount of crystallinity and the spherulite size are predicted as a function of fiber spacing and packing geometry, and the predictions are found to be in good agreement with experimental results obtained on polyphenylenesulfide/carbon fiber composites. The advantages of our approach over the continuum approach is that a relatively accurate prediction of the spherulite size is possible due to constraints imposed by the fiber on the spherulitic growth.en
dc.description.degreePh. D.en
dc.format.extentxvi, 203 leavesen
dc.format.mediumBTDen
dc.format.mimetypeapplication/pdfen
dc.identifier.otheretd-10122005-134439en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-10122005-134439/en
dc.identifier.urihttp://hdl.handle.net/10919/39780en
dc.language.isoenen
dc.publisherVirginia Techen
dc.relation.haspartLD5655.V856_1991.K444.pdfen
dc.relation.isformatofOCLC# 25624705en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V856 1991.K444en
dc.subject.lcshCarbon fibers -- Thermal properties -- Measurementen
dc.subject.lcshThermoplastic composites -- Thermal properties -- Measurementen
dc.titleA numerical and experimental investigation of the effects of thermal history on the structure/property relationship of PPS/carbon fiber compositesen
dc.typeDissertationen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemical Engineeringen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.leveldoctoralen
thesis.degree.namePh. D.en

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