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Structural studies of precursor and partially oxidized conducting complexes. XI. A neutron diffraction study of barium dibromotetracyanoplatinate(IV) hydrate

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dc.contributor.authorKoch, Timothy R.en
dc.contributor.authorJohnson, Paul L.en
dc.contributor.authorWashecheck, Donald M.en
dc.contributor.authorCornish, Thomas L.en
dc.contributor.authorWilliams, Jack M.en
dc.date.accessioned2022-08-17T19:40:14Zen
dc.date.available2022-08-17T19:40:14Zen
dc.date.issued1977-10-01en
dc.date.updated2022-08-06T22:01:51Zen
dc.description.abstractBa[Pt(CN)<sub>4</sub>Br<sub>2</sub>].4.5H<sub>2</sub>O, tetragonal, P4/ mnc (D<sub>4h</sub><sup>6</sup>,), a = 9.425 (3), c = 17.085 (6) A, Z = 4, D<sub>m</sub> = 2.96, D<sub>c</sub> = 2.96 g cm<sup>-3</sup>. The structure was determined by direct methods. 2842 reflections were collected with single-crystal neutron-diffraction techniques and yielded 1217 independent reflections upon averaging; these were refined to an agreement factor of R(Fo2)=0.056 for all observed data and R(F<sub>O</sub><sup>2</sup>)= 0.053 for 999 data with F<sub>O</sub><sup>2</sup> > lσ (F<sub>O</sub><sup>2</sup>). The structure consists of octahedrally coordinated Pt<sup>IV</sup> metal atoms, one Ba<sup>2+</sup> ion, and two H<sub>2</sub>O molecules (one O and five H atoms are in crystallographic disorder). The Ba<sup>2+</sup> ion is highly coordinated with nine nearest neighbors.en
dc.description.versionPublished versionen
dc.format.extentPages 3249-3251en
dc.format.mimetypeapplication/pdfen
dc.identifier.doihttps://doi.org/10.1107/s0567740877010723en
dc.identifier.issn0567-7408en
dc.identifier.issue10en
dc.identifier.orcidKoch, Timothy [0000-0002-8026-9653]en
dc.identifier.urihttp://hdl.handle.net/10919/111541en
dc.identifier.volume33en
dc.language.isoenen
dc.publisherInternational Union of Crystallographyen
dc.rightsPublic Domain (U.S.)en
dc.rights.urihttp://creativecommons.org/publicdomain/mark/1.0/en
dc.titleStructural studies of precursor and partially oxidized conducting complexes. XI. A neutron diffraction study of barium dibromotetracyanoplatinate(IV) hydrateen
dc.title.serialActa Crystallographica Section B Structural Crystallography and Crystal Chemistryen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/VT Carilion School of Medicineen
pubs.organisational-group/Virginia Tech/VT Carilion School of Medicine/Internal Medicineen
pubs.organisational-group/Virginia Tech/VT Carilion School of Medicine/Internal Medicine/General IMen

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