Predispersed solvent extraction of copper from dilute aqueous solution

Simple item page
dc.contributor.authorRodarte, Alma Isabel Marínen
dc.contributor.committeecochairWills, George B.en
dc.contributor.committeecochairConger, William L.en
dc.contributor.committeememberMichelsen, Donald L.en
dc.contributor.committeememberBeyer, Gerhard H.en
dc.contributor.committeememberBoardman, Gregory D.en
dc.contributor.departmentChemical Engineeringen
dc.date.accessioned2014-03-14T21:16:18Zen
dc.date.adate2008-07-28en
dc.date.available2014-03-14T21:16:18Zen
dc.date.issued1991-09-20en
dc.date.rdate2008-07-28en
dc.date.sdate2008-07-28en
dc.description.abstractPredispersed Solvent Extraction (POSE) was used to extract copper ions from dilute acidic aqueous solution. POSE is based on the principle that there is no need to comminute both phases. All that is necessary is to comminute the solvent phase prior to contacting it with the feed. This is done by converting the solvent into aphrons. which are micron-sized globules encapsulated in a soapy film. Since the aphrons are so small, it takes a long time for the solvent to rise to the surface under the influence of gravity alone. Therefore, the separation is expedited by piggy-back flotation of the aphrons on especially prepared gas bubbles, which are somewhat larger than aphrons and are called colloidal gas aphrons (CGA). Polyaphrons of various types were studied extensively. The apparatus used to generate the polyaphrons was upgraded. The residence time distribution of a liquid in the polyaphron generator was determined. The particle size distribution of polyaphrons was determined using photo-microscopy and sedimentation among other methods. Batch tests were done using both conventional and POSE. Results showed that POSE approaches equilibrium much faster than conventional extraction. Equilibrium isotherms were drawn and empirical equilibrium relationships were developed. The dynamics of the kinetics of the extraction was modeled using film theory. Equipment for the POSE process was built. Experiments were carried out in continuous mode and the process was optimized. An empirical statistical equation was developed for the extraction process in continuous mode. Depending on the aqueous to solvent ration, more than 99% copper can be extracted.en
dc.description.degreePh. D.en
dc.format.extentxix, 267 leavesen
dc.format.mediumBTDen
dc.format.mimetypeapplication/pdfen
dc.identifier.otheretd-07282008-134126en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-07282008-134126/en
dc.identifier.urihttp://hdl.handle.net/10919/38846en
dc.language.isoenen
dc.publisherVirginia Techen
dc.relation.haspartLD5655.V856_1991.R622.pdfen
dc.relation.isformatofOCLC# 25145964en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V856 1991.R622en
dc.subject.lcshCopper -- Solubilityen
dc.titlePredispersed solvent extraction of copper from dilute aqueous solutionen
dc.typeDissertationen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemical Engineeringen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.leveldoctoralen
thesis.degree.namePh. D.en

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
LD5655.V856_1991.R622.pdf
Size:
9.81 MB
Format:
Adobe Portable Document Format
Download

Collections

Doctoral Dissertations