An Investigation of the Structure-Property Relationships for High Performance Thermoplastic Matrix, Carbon Fiber Composites with a Tailored Polyimide Interphase

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dc.contributor.authorGardner, Slade Havelock IIen
dc.contributor.committeechairDavis, Richey M.en
dc.contributor.committeememberWilkes, Garth L.en
dc.contributor.committeememberMarand, Evaen
dc.contributor.committeememberReifsnider, Kenneth L.en
dc.contributor.committeememberLesko, John J.en
dc.contributor.committeememberRiffle, Judy S.en
dc.contributor.departmentChemical Engineeringen
dc.date.accessioned2014-03-14T20:22:41Zen
dc.date.adate1998-06-10en
dc.date.available2014-03-14T20:22:41Zen
dc.date.issued1998-08-17en
dc.date.rdate1999-06-10en
dc.date.sdate1998-08-17en
dc.description.abstractThe aqueous suspension prepregging technique was used to fabricate PEEK and PPS matrix composites with polyimide interphases of tailored properties. The structure-property relationships of Ultem-type polyimide and BisP-BTDA polyimide which were made from various water soluble polyamic acid salts were studied. The molecular weight of the polyimides was shown to be dependant upon the selection of the base used for making the polyamic acid salt. The development of an Ultem-type polyimide with controlled molecular weight and properties similar to commercial Ultem 1000 was accomplished with the Ultem-type TPA+ polyamic acid salt. Both the Ultem-type polyimides and the BisP-BTDA polyimides derived from the NH4+ salt and the TMA+ salt were shown to crosslink at elevated temperatures. Blends of Ultem-type polyimide with PEEK and BisP-BTDA polyimide with PEEK were prepared to study the structure-property relationships of model composite matrices. Since both polyimides are miscible with PEEK, interdiffusion of the polyimides with PEEK is expected, however, the interdiffusion behavior is complicated by the crosslinking mechanism of the polyimides. Ultem-type polyimide interphase, PEEK matrix composites and BisP-BTDA polyimide interphase, PEEK matrix composites were fabricated using the aqueous suspension prepregging technique and evaluated to determine the effects of the interphase properties on the bulk composite performance and durability. Three different Ultem-type polyimides from the NH4+, TMA+ and TPA+ polyamic acid salts were used and two different BisP-BTDA polyimides from the NH4+ and TMA+ polyamic acid salts were used. The transverse flexure strength was used to qualitatively rank the composites by level of interfacial shear strength. The longitudinal tensile strength of the composites was shown to vary with relative interfacial shear strength. The trend of these data qualitatively support the existence of a maximum longitudinal tensile strength at an optimum interfacial shear strength. Notched fatigue testing of the Ultem-type polyimide interphase, PEEK matrix composites showed that the initial split growth rate increased with decreasing relative interfacial shear strength. Ultem-type polyimide interphase, PPS matrix composites were fabricated using the aqueous suspension prepregging technique and evaluated to determine the effects of the interphase properties on the bulk composite performance. Three different Ultem-type polyimides from the NH4+, TMA+ and TPA+ polyamic acid salts were used. The transverse flexure strength was used to qualitatively rank the composites by level of interfacial shear strength. The longitudinal tensile strength of the composites was shown to vary with relative interfacial shear strength. The trend of these data qualitatively support the existence of a maximum longitudinal tensile strength at an optimum interfacial shear strength.en
dc.description.degreePh. D.en
dc.identifier.otheretd-92098-221727en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-92098-221727/en
dc.identifier.urihttp://hdl.handle.net/10919/30757en
dc.publisherVirginia Techen
dc.relation.haspartshgthsis.pdfen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjectpolyamic aciden
dc.subjectpolyimideen
dc.subjectinterphaseen
dc.subjectcompositeen
dc.titleAn Investigation of the Structure-Property Relationships for High Performance Thermoplastic Matrix, Carbon Fiber Composites with a Tailored Polyimide Interphaseen
dc.typeDissertationen
thesis.degree.disciplineChemical Engineeringen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.leveldoctoralen
thesis.degree.namePh. D.en

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