Browsing by Author "Godrej, Adil N."
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- Addressing the Contribution of Indirect Potable Reuse to Inland Freshwater SalinizationBhide, Shantanu V.; Grant, Stanley B.; Parker, Emily A.; Rippy, Megan A.; Godrej, Adil N.; Kaushal, Sujay S.; Prelewicz, Gregory; Saji, Niffy; Curtis, Shannon; Vikesland, Peter J.; Maile-Moskowitz, Ayella; Edwards, Marc A.; Lopez, Kathryn; Birkland, Thomas A.; Schenk, Todd (2021-02-02)Inland freshwater salinity is rising worldwide, a phenomenon called the freshwater salinization syndrome (FSS). We investigate a potential conflict between managing the FSS and indirect potable reuse, the practice of augmenting water supplies through the addition of reclaimed wastewater to surface waters and groundwaters. From time-series data collected over 25 years, we quantify the contributions of three salinity sources—a wastewater reclamation facility and two rapidly urbanizing watersheds—to the rising concentration of sodium (a major ion associated with the FSS) in a regionally important drinking water reservoir in the Mid-Atlantic United States. Sodium mass loading to the reservoir is primarily from watershed runoff during wet weather and reclaimed wastewater during dry weather. Across all timescales evaluated, sodium concentration in the reclaimed wastewater is higher than in outflow from the two watersheds. Sodium in reclaimed wastewater originates from chemicals added during wastewater treatment, industrial and commercial discharges, human excretion, and down-drain disposal of drinking water and sodium-rich household products. Thus, numerous opportunities exist to reduce the contribution of indirect potable reuse to sodium pollution at this site, and the FSS more generally. These efforts will require deliberative engagement with a diverse community of watershed stakeholders and careful consideration of the local political, social, and environmental context.
- Analysis of an Urban Stormwater Bioretention Management Practice in Prince William County, VirginiaAngelo, Suzanne (Virginia Tech, 2005-11-21)The performance of an urban stormwater bioretention management practice in the Kingsbrooke Subdivision of Prince William County, Virginia was examined over a one-year period. Bioretention is a relatively new urban stormwater best management practice (BMP) intended to mimic the pollutant-removal characteristics of an upland forest habitat. Typical bioretention areas utilize shallow ponding and highly-infiltrative sandy soils to treat the stormwater runoff from small commercial or residential drainage sites. The Kingsbrooke bioretention area was found to be atypical in several ways, including its relatively large, 14 acre, drainage area and the high clay content of its topsoil. Hydrologic and chemical data were collected by Virginia Tech staff for a total of 8 months in 2003 and 2004. Analysis of pollutant loading data was complicated by the presence of three unmeasured water flows: overland inflow bypassing the inflow gage, and groundwater flows both entering and exiting the bioretention soils. The BMP did reduce peak runoff rates for some storms, but did not significantly reduce total storm volumes because of the combined effects of the large drainage area to BMP area ratio and the poor infiltration capacity of the soil. Pollutant load calculations determined that the site removed about 28% of total suspended solids, 32% of total phosphorus, and about 15% of total nitrogen. Removals of approximately 16% and 7% were observed for lead and zinc, respectively. Although the Kingsbrooke bioretention area did improve water quality, the pollutant removal efficiencies were lower than those reported in the literature from more conventional bioretention areas.
- Application of system dynamics modeling techniques to an existing stream water quality modelFinley, Allan Michael (Virginia Tech, 1991-05-05)From the results of this project and report the following conclusions seem warranted: 1. The actual behavior of any real stream system, subject to a point load, is dependent on an extremely complex and integrated network of events which can occur in series or parallel. 2. The QUAL2E model considers the major events or cycles of a stream system in a fully integrated manner, offers the user many configuration options, and provides for a wealth of essential output data. The documentation provides reasonable explanation as to the means by which the model simulates a stream system. The QUAL2E model can be executed successfully by the first time user with minimal effort. 3. The DYNAMO model can be effectively invoked through the use of differential equations that can be translated into suitable DYNAMO expressions. The model is easy to learn and can be executed by the first time user with minimal effort. 4. Input parameters and initial conditions for the both the QUAL2E and DYNAMO models were reasonable for the purpose intended. That being the comparison of the behavior of the two systems.
- Breakpoint Chlorination as an Alternate means for Ammoia-Nitrogen removal at a Water Reclamation PlantBrooks, Matthew A. (Virginia Tech, 2004-02-04)Numerous wastewater treatment processes are currently available for nitrogen removal or ammonia conversion to nitrate. Those that are economically feasible rely mostly on microbiological processes, which are only effective when the microorganisms remain in a healthy state. If a biological process upset was to occur, due to a toxic shock load or cold weather, it may result in a discharge of ammonia or total nitrogen into the receiving water body. The impact of such a discharge could have deleterious effects on aquatic life or human health. The main objective of the breakpoint pilot study was to define optimum breakpoint pilot plant operating conditions which could then be applied to the design of a full scale breakpoint facility and serve as an emergency backup to biological nitrification. A pilot study was built on site at the Upper Occoquan Sewage Authority's Regional Water Reclamation Facility in Centreville Virginia. Testing was conducted in two phases (I and II) over a two year period in order to determine the operating conditions at which the breakpoint reaction performed best. Tests were performed during Phase I to determine the optimum operating pH, Cl₂:NH₃-N dose ratio, S0₂:Cl₂ dose ratio, and the minimum detention time for completion of the breakpoint reaction. Other testing done during Phase I included several special studies; including examination of appropriate analytical methods for monitoring breakpoint reactions, and investigation of the breakpoint reaction by-product nitrogen trichloride. Phase II testing examined how varying breakpoint operating temperatures, varying influent ammonia concentrations, higher influent organic nitrogen concentrations, and higher influent nitrite concentrations influenced the performance of the breakpoint pilot operation. Averages of data from operation at three different rapid mix pHs (7.0, 7.5, and 8.0) showed that pilot performance (i.e., ammonia oxidation) improved and the reaction was more stable at the higher operating pHs 7.5 and 8.0. Examination of dose ratios used during the study showed that the ideal operating ratios for this particular water was around 8:1 Cl₂:NH₃-N for the breakpoint reaction and 1.3:1 S0₂:Cl₂ for the dechlorination reaction. Although detention times for completion of the breakpoint reaction varied with pilot influent temperature, it generally required around 30-35 minutes to reach ammonia concentrations of < 0.2 mg/L NH₃-N at 8-12°C. Completion of the breakpoint reaction was found to be quickest at 20°C (the highest water temperature tested at the pilot). The tests of varying influent ammonia concentrations showed that although higher influent ammonia concentrations (11.0 mg/L) resulted in faster ammonia oxidation rates initially, the pilot operated better and had the same final performance results when the influent ammonia was lowered. Increasing the organic nitrogen concentrations (~ 1.0 mg/L) in the pilot influent resulted in a slightly higher Cl₂:NH₃-N dose ratio needed to reach breakpoint, a higher S0₂:Cl₂ dose needed to dechlorinate, and resulted in the formation of numerous disinfection byproducts. Increasing the nitrite concentration in the pilot influent increased the chlorination dose requirement.
- The Challenges and Opportunities in Monitoring and Modeling Waterborne Pathogens in Water- and Resource-Restricted Africa: Highlighting the critical need for multidisciplinary research and tool advancementHolcomb, Megan Kathleen (Virginia Tech, 2014-01-22)Water is a primary shared resource that connects all species across the landscape and can facilitate shared exposure to a community of waterborne pathogens. Despite remarkable global progress in sanitation and hygiene development in the past two decades, infectious diarrhea remains a prominent public health threat in sub-Saharan Africa. This thesis identifies and discusses persistent challenges limiting the success of current waterborne disease management strategies and several existing research hurdles that continue to impede characterization of microbial transmission and transport. In this work, the Chobe River watershed in Northern Botswana serves as a target study site for the application of hydrological modeling tools to quantify emergent water quality and health challenges in Southern Africa. A watershed model with extensive data requirements, the Hydrological Simulation Program – Fortran (HSPF), is used to identify primary data gaps and model assumptions that limit the progress of model development, and guide opportunities for data collection, tool development, and research direction. Environmental pathogen exposure risk and epidemiological outbreak dynamics are best described by interactions between the coupled human and environmental processes within a system. The challenge of reducing diarrheal disease incidence strengthens a call for research studies and management plans that join multiple disciplines and consider a range of spatiotemporal scales.
- Cod removal, nitrification and denitrification kinetics and mathematical modeling of an integrated fixed film activated sludge (IFAS) systemSen, Dipankar (Virginia Tech, 1995)Biological nitrogen and phosphorus removal are being recommended at several wastewater treatment facilities in the U.S. to control eutrophication in water bodies receiving their effluent. In several instances, nitrogen removal is being recommended on a year round basis at plants located in the temperate climates. Concerns have been raised regarding the cost of additional reactors and clarifiers required for nitrogen removal in winter using activated sludge systems. Several facilities do not have the space to construct additional units. This research was undertaken to evaluate the potential for reducing reactor and clarifier requirements, maximize use of existing facilities, and economize costs for year round nitrification and nitrogen removal. The purpose was to develop Integrated Fixed Film Activated Sludge Systems in which biofilm support media was installed in the activated sludge basins to enhance nitrogen removal. The objectives were to evaluate the COD removal, nitrification and denitrification kinetics, which would help develop design and mathematical models for the process, and optimize the layout in terms of costs and media required for nitrogen removal. A bench scale pilot study was undertaken in conjunction with two full scale studies with two types of media: (i) free floating media and (ii) media fixed in frames. Amongst biofilm support media in the first category, sponge cuboids (Captor) were selected. For the second category, rope type Ringlace media was selected. Following preliminary screening for satisfactorily simulation of full scale conditions in a bench scale system, the IFAS-Sponge system was selected for kinetic coefficient evaluation and IF AS system model development.
- A Complex, Linked Watershed-Reservoir Hydrology and Water Quality Model Application for the Occoquan Watershed, VirginiaXu, Zhongyan (Virginia Tech, 2005-12-16)The Occoquan Watershed is a 1515 square kilometer basin located in northern Virginia and contains two principal waterbodies: the Occoquan Reservoir and Lake Manassas. Both waterbodies are principal drinking water supplies for local residents and experience eutrophication and summer algae growth. They are continuously threatened by new development from the rapid expansion of the greater Washington D.C. region. The Occoquan model, consisting of six HSPF and two CE-QUAL-W2 submodels linked in a complex way, has been developed and applied to simulate hydrology and water quality activities in the two major reservoirs and the associated drainage areas. The studied water quality constituents include temperature, dissolved oxygen, ammonium nitrogen, oxidized nitrogen, orthophosphate phosphorus, and algae. The calibration of the linked model is for the years 1993-95, with a validation period of 1996-97. The results show that a successful calibration can be achieved using the linked approach, with moderate additional effort. The spatial and temporal distribution of hydrology processes, nutrient detachment and transport, stream temperature and dissolved oxygen were well reproduced by HSPF submodels. By using the outputs generated by HSPF submodels, the CE-QUAL-W2 submodels adequately captured the water budgets, hydrodynamics, temperature, temporal and spatial distribution of dissolved oxygen, ammonium nitrogen, oxidized nitrogen, orthophosphate phosphorus, and algae in Lake Manassas and Occoquan Reservoir. This demonstrates the validity of linking two types of state of the art water quality models: the watershed model HSPF and the reservoir model CE-QUAL-W2. One of the advantages of the linked model approach is to develop a direct cause and effect relationship between upstream activities and downstream water quality. Therefore, scenarios of various land use proposals, BMP implementation, and point source management can be incorporated into HSPF applications, so that the CE-QUAL-W2 submodels can use the boundary conditions corresponding with these scenarios to predict the water quality variations in the receiving waterbodies. In this research, two land use scenarios were developed. One represented the background condition assuming all the land covered by forest and the other represented the environmental stress posed by future commercial and residential expansion. The results confirm the increases of external nutrient loads due to urbanization and other human activities, which eventually lead to nutrient enrichment and enhanced algae growth in the receiving waterbodies. The increases of external nutrient loads depend on land use patterns and are not evenly spread across the watershed. The future development in the non urban areas will greatly increase the external nutrient production and BMPs should be implemented to reduce the potential environmental degradation. For the existing urban areas, the model results suggest a potential threshold of nutrient production despite future land development. The model results also demonstrate the catchment function of Lake Manassas in reducing nutrient transport downstream.
- Concentration profiles and mapping of ambient air quality in the Shenandoah National ParkGodrej, Adil N. (Virginia Polytechnic Institute and State University, 1982)A graphical system was developed to represent airborne air quality monitoring data. The representations developed included three—dimensional spatial mapping, percentage and frequency distributions, and altitude—based scatter diagrams. Elementary statistical analyses and correlations of the measured parameters were also performed. Data gathered in eight flights to the Shenandoah National Park during the summer months of 1981 were analyzed. Sulfur dioxide levels were found to be in the 5 - 15 ppb range, nitrogen oxides were in the 4 — 10 ppb range, nitrous oxide was in the 2 - 5 ppb range, nitrogen dioxide was in the 2 - 5 ppb range, ozone was in the 35 - 70 ppb range and visual range was in the 5 — 90 mile range. The data representation system proved to be an easier and more useful method of displaying the data than the previously existing system.
- A Decision Support System for Indirect Potable Reuse Based on Integrated ModelingLodhi, Adnan Ghaffar (Virginia Tech, 2019-07-01)Optimal operation of water reclamation facilities (WRFs) is critical for an indirect potable reuse (IPR) system, especially when the reclaimed water constitutes a major portion of the reservoir's safe yield. It requires timely and informed decision-making in response to the fluctuating operational conditions, e.g., weather patterns, plant performance, water demand, etc. Advanced integrated modeling techniques can be used to develop reliable operational strategies to mitigate future risks associated with water quality without needing high levels of financial investment. The Upper Occoquan Service Authority (UOSA) WRF, located in northern Virginia, discharges nitrified reclaimed water directly into a tributary of the Occoquan Reservoir, one of the major water supply sources for Fairfax County. Among the many operational challenges at UOSA, one is to regulate the nitrate concentration in its reclaimed water based on the denitrifying capacity of the reservoir. This study presents an integrated model that is used to predict future reservoir conditions based on the weather and streamflow forecasts obtained from the Climate Forecast System and the National Water Model. The application captures the dynamic transformations of the pollutant loadings in the streams, withdrawals by the water treatment plant, WRF effluent flows, and plant operations to manage the WRF performance. It provides plant operators with useful feedback for correctly targeting the effluent nitrates using an intelligent process simulator called IViewOps. The platform is powered by URUNME, a new software that fully automates the operation of the reservoir and process models integrating forecasting products, and data sources. URUNME was developed in C#.NET to provide out-of-the-box functionality for model coupling, data storage, analysis, visualization, scenario management, and decision support systems. The software automatically runs the entire integrated model and outputs data on user-friendly dashboards, displaying historical and forecasting trends, on a periodic basis. This decision support system can provide stakeholders with a holistic view for the design, planning, risk assessments, and potential improvements in various components of the water supply chain, not just for the Occoquan but for any reservoir augmentation type IPR system.
- A decision support system for indirect potable reuse based on integrated modeling and futurecastingLodhi, A.G.; Godrej, Adil N.; Sen, D.; Angelotti, R.; Brooks, M. (IWA, 2019-04-09)Optimal operation of water reclamation facilities (WRFs) is critical for an indirect potable reuse (IPR) system, especially when the reclaimed water constitutes a major portion of the safe yield, as in the case of the Occoquan Reservoir located in Northern Virginia. This paper presents how a reservoir model is used for predicting future reservoir conditions based on the weather and streamflow forecasts obtained from the Climate Forecast System and the National Water Model. The resulting model predictions provide valuable feedback to the operators for correctly targeting the effluent nitrates using plant operations and optimization model called IViewOps (Intelligent View of Operations). The integrated models are run through URUNME, a newly developed integrated modeling software, and form a decision support system (DSS). The system captures the dynamic transformations in the nutrient loadings in the streams, withdrawals by the water treatment plant, WRF effluent flows, and the plant operations to manage nutrient levels based on the nitrate assimilative capacity of the reservoir. The DSS can provide multiple stakeholders with a holistic view for design, planning, risk assessments, and potential improvements in various components of the water supply chain, not just in the Occoquan but also in any reservoir augmentation-type IPR system.
- DESIGN THINKING for Visualizing Acid-Base Chemistry - Documenting a user-centered approach for designing and developing an ADA compliant online tool for visualizing acid-base chemistryStamper, Michael J.; Briganti, Jonathan; Brown, Anne M.; Dietrich, Andrea M.; Godrej, Adil N.; Schreiber, Madeline E.; Walz, Anita R. (2019-07-17)This project created an online tool, that we call “The pkAnalyzer”. It enables the exploration of acid-conjugate base distributions in an easy to use Web interface. This project is also an example of the disciplines of Arts and Design into the STEM sciences, i.e. STEM to STEAM, and University Libraries commitment to faculty, students, and staff throughout the Virginia Tech system, in the areas of data visualization and design services to aid in the research process and communication of results. Beyond the functionality of the tool, this project involved the planning and designing a custom, modifiable, and attractive user interface (UI) and visualization that are "user-friendly", and incorporate the World Wide Web Consortium’s Web Content Accessibility Guidelines (WCAG), and falls with the Federal Governement’s Section 508 guidelines pertaining to creating and maintaining information and communications technology (ICT) that is accessible to people with disabilities relating to vision. Using a "Design Thinking" approach, all aspects of the design of this tool – User Interface (UI), User Experience (UX), Interaction Design (IxD), Graphic – were taken into account, and developed to enhance the user's experience using the tool, and undertanding of a complex chemical concept that is widely used in the basic and applied sciences and engineering.
- Development and Evaluation of Infilling Methods for Missing Hydrologic and Chemical Watershed Monitoring DataJohnston, Carey Andrew (Virginia Tech, 1999-08-24)Watershed monitoring programs generally do not have perfect data collection success rates due to a variety of field and laboratory factors. A major source of error in many stream-gaging records is lost or missing data caused by malfunctioning stream-side equipment. Studies estimate that between 5 and 20 percent of stream-gaging data may be marked as missing for one reason or another. Reconstructing or infilling missing data methods generate larger sets of data. These larger data sets generally generate better estimates of the sampled parameter and permit practical applications of the data in hydrologic or water quality calculations. This study utilizes data from a watershed monitoring program operating in the Northern Virginia area to: (1) identify and summarize the major reasons for the occurrence of missing data; (2) provide recommendations for reducing the occurrence of missing data; (3) describe methods for infilling missing chemical data; (4) develop and evaluate methods for infilling values to replace missing chemical data; and (5) recommend different infilling methods for various conditions. An evaluation of different infilling methods for chemical data over a variety of factors (e.g., amount of annual rainfall, whether the missing chemical parameter is strongly correlated with flow, amount of missing data) is performed using Monte Carlo modeling. Using the results of the Monte Carlo modeling, a Decision Support System (DSS) is developed for easy application of the most appropriate infilling method.
- Development of a Design-Based Computational Model of Bioretention SystemsLiu, Jia (Virginia Tech, 2013-12-03)Multiple problems caused by urban runoff have emerged as a consequence to the continuing development of urban areas in recent decades. The increase of impervious land areas can significantly alter watershed hydrology and water quality. Typical impacts to downstream hydrologic regimes include higher peak flows and runoff volumes, shorter concentration times, and reduced infiltration. Urban runoff increases the transport of pollutants and nutrients and thus degrades water bodies adjacent to urban areas. One of the most frequently used practices to restore the hydrology and water quality of urban watersheds is bioretention (also known as a rain garden). Despite its wide applicability, an understanding of its multiple physiochemical and biological treatment processes remains an active research area. To provide a wide ability to evaluate the hydrologic input to bioretention systems, spatial and temporal distribution of storm events in Virginia were studied. Results generated from long-term frequency analysis of 60-year precipitation data demonstrate that the 90 percentile, or 10-year return period rainfall depth and dry duration in Virginia are between 22.9 – 35.6 mm and 15.3 – 25.8 days, respectively. Monte-Carlo simulations demonstrated that sampling programs applied in different regions would likely encounter more than 30% of precipitation events less than 2.54 mm, and 10% over 25.4 mm. Further experimental research was conducted to evaluate bioretention recipes for retaining stormwater nitrogen (N) and phosphorus (P). A mesocosm experiment was performed to simulate bioretention facilities with 3 different bioretention blends as media layers with underdrain pipes for leachate collection. A control group with 3 duplicates for each media was compared with a replicated vegetated group. Field measurement of dissolved oxygen (DO), oxidation-reduction potential (ORP), pH, and total dissolved solids (TDS) was combined with laboratory analyses of total suspended solids (TSS), nitrate (NO3), ammonium (NH4), phosphate (PO4), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) to evaluate the nutrient removal efficacies of these blends. Physicochemical measurements for property parameters were performed to determine characteristics of blends. Isotherm experiments to examine P adsorption were also conducted to provide supplementary data for evaluation of bioretention media blends. The results show that the blend with water treatment residuals (WTR) removed >90% P from influent, and its effluent had the least TDS / TSS. Another blend with mulch-free compost retained the most (50 – 75%) total nitrogen (TN), and had the smallest DO / ORP values, which appears to promote denitrification under anaerobic conditions. Increase of hydraulic retention time (HRT) to 6 h could influence DO, ORP, TKN, and TN positively. Plant health should also be considered as part of a compromise mix that sustains vegetation. Two-way analysis of variance (ANOVA) found that single and interaction effects of HRT and plants existed, and could affect water quality parameters of mesocosm leachate. Based upon the understanding of the physiochemical and hydrologic conditions mentioned previously, a design model of a bioretention system became the next logical step. The computational model was developed within the Matlab® programming environment to describe the hydraulic performance and nutrient removal of a bioretention system. The model comprises a main function and multiple subroutines for hydraulics and treatment computations. Evapotranspiration (ET), inflow, infiltration, and outflow were calculated for hydrologic quantitation. Biomass accumulation, nitrogen cycle and phosphorus fate within bioretention systems were also computed on basis of the hydrologic outputs. The model was calibrated with the observed flow and water quality data from a field-scale bioretention in Blacksburg, VA. The calibrated model is capable of providing quantitative estimates on flow pattern and nutrient removal that agree with the observed data. Sensitivity analyses determined the major factors affecting discharge were: watershed width and roughness for inflow; pipe head and diameter for outflow. Nutrient concentrations in inflow are very influential to outflow quality. A long-term simulation demonstrates that the model can be used to estimate bioretention performance and evaluate its impact on the surrounding environment. This research advances the current understanding of bioretention systems in a systematic way, from hydrologic behavior, monitoring, design criteria, physiochemical performance, and computational modeling. The computational model, combined with the results from precipitation frequency analysis and evaluation of bioretention blends, can be used to improve the operation, maintenance, and design of bioretention facilities in practical applications.
- Development of a Guide to Lake and Reservoir Zone DeterminationSaji, Niffy (Virginia Tech, 2008-03-17)Reservoirs are generally created by damming rivers. The upper reaches of any reservoir is generally narrow and winding like the parent river. This is the riverine zone of the reservoir. The reservoir is deepest and widest near the dam. Here, lake-like conditions exist and the water is quiescent. This is the lacustrine zone. The transitional zone separates the lacustrine and riverine zone. It has intermediate characteristics. There are many characteristics, both physical and chemical, that differentiate between these three zones. Based on the differences in characteristics between the three zones, a method has been developed to successfully divide any reservoir into three zones. The method developed was applied to Lake Manassas and the Occoquan Reservoir located in the Occoquan watershed in Virginia. Both are man-made impoundments. Analysis of data, based on the method developed, was successfully in dividing both reservoirs into the three zones. This method may therefore be successfully applied to obtain zonation in reservoirs.
- Development of a Web-Based System for Water Quality Data Management and VisualizationYang, Wei (Virginia Tech, 2010-05-03)With increasing urbanization and population growth, humankind faces multiple environmental challenges. Stresses on limited resources, especially water resources, are now greater than ever before. Watershed monitoring and management are important components of programs to abate water resource stresses. The increasing water quantity and quality monitoring has produced a need for better data management techniques to manage the vast amount of watershed monitoring data being observed. These data must be stored, error checked, manipulated, retrieved and shared with the watershed management community. The web-based data visualization and analysis technology has played a critical role in all aspects of watershed management. Especially in recent years, computer-assisted data analysis has matured enormously. This maturing technology makes web-based visualization and analysis technology change its role to become an integrated system which combines applications of databases, and internet technology. The main objective of this study is to develop a prototype system which has ability of data visualization and analysis. Microsoft SQL Server is used to build a comprehensive database, which includes all datasets collected by OWML. A Web-Based Data Visualization and Analysis System which provides an integrated interface for permitted users to explore, analyze and download data has been developed.
- Development of Transitional Settling Regimen Parameters to Characterize and Optimize Solids-liquid Separation PerformanceMancell-Egala, Abdul Salim (Virginia Tech, 2016-09-20)Novel settling characteristic metrics were developed based on the fundamental mechanisms of coagulation, flocculation, and settling. The settling metrics determined parameters that are essential in monitoring and optimizing the activated sludge process without the need for expensive or specialized equipment. Current settling characteristic measurements that don't require specialized instruments such as sludge volume index (SVI) or initial settling velocity (ISV), have no fundamental basis in solid-liquid separation and only indicate whether settling is good or bad without providing information as to limitations present in a sludge matrix. Furthermore, the emergence of aerobic granulation as a potential pathway to mitigate solid-separation issues further stresses the need for new settling characteristic metrics to enable integration of the new technology with the current infrastructure. The granule or intrinsic aggregate fraction in different types was of sludge was quantified by simulating different surface overflow rates (SOR). The technique named Intrinsic Settling Classes (ISC) was able to separate granules and floc by simulating high SOR values due to the lack of a flocculation time needed for granules. The method had to be performed in a discrete settling environment to characterize a range of flocculation behavior and was able to classify the granular portion of five different types of sludge. ISC was proven to accurately (±2%) determine the granule fraction and discrete particle distribution. The major significance of the test is its ability to show if a system is producing particles that will eventually grow to become granules. This methodology proved to be very valuable in obtaining information as to the granular fraction of sludge and the granular production of a system. Flocculent settling (stokesian) was found to be predominant within ideally operating clarifiers, and the shift to 'slower' hindered settling (non-stokesian) causes both failure and poor effluent quality. Therefore, a new metric for settling characteristics was developed and classified as Limit of Stokesian Settling (LOSS). The technique consisted of determining the total suspended solids (TSS) concentration at which mixed liquor settling characteristics transition from stokesian to non–stokesian settling. An image analytical technique was developed with the aid of MATLAB to identify this transition. The MATLAB tool analyzed RGB images from video, and identified the presence of an interface by a dramatic shift in the Red indices. LOSS data for Secondary activated-sludge systems were analyzed for a period of 60 days at the Blue Plains Advanced Wastewater Treatment Plant. LOSS numbers collected experimentally were validated with the Takacs et al. (1991) settling model. When compared to flux curves with small changes in the sludge concentration matrix, LOSS was found to be faster at characterizing the hindered settling velocity and was less erratic. Simple batch experiments based on the critical settling velocity (CSV) selection were used as the basis for the development of two novel parameters: threshold of flocculation/flocculation limitation (TOF/a), and floc strength. TOF quantified the minimum solids concentration needed to form large flocs and was directly linked to collision efficiency. In hybrid systems, an exponential fitting on a CSV matrix was proposed to quantify the collision efficiency of flocs (a). Shear studies were conducted to quantify floc strength. The methods were applied to a wide spectrum of sludge types to show the broad applicability and sensitivity of the novel methods. Three different activated sludge systems from the Blue Plains AWWTP were monitored for a 1 year period to explore the relationship between effluent suspended solids (ESS) and activated sludge settling and flocculation behavior. Novel metrics based on the transitional solids concentration (TOF, and LOSS) were also collected weekly. A pilot clarifier and settling column were run and filmed to determine floc morphological properties. SVI was found to lose sensitivity (r < 0.20) when characterizing ISV above a hindered settling rate of 3 m h-1. ISV and LOSS had a strong correlation (r = 0.71), but ISV was subject to change, depending on the solids concentration. Two sludge matrix limitations influencing ESS were characterized by transition concentrations; pinpoint floc formation, and loose floc formation. Pinpoint flocs had TOF values above 400 mg TSS L-1; loose floc formation sludge had TOF and LOSS values below 400 mg TSS L-1 and 900 mg TSS L-1, respectively. TOF was found to correlate with the particle size distribution while LOSS correlated to the settling velocity distribution. The use of both TOF and LOSS is a quick and effective way to characterize limitations affecting ESS.
- Diffuser Fouling Mitigation, Wastewater Characteristics And Treatment Technology impact on Aeration EfficiencyOdize, Victory Oghenerabome (Virginia Tech, 2018-04-18)Achieving energy neutrality has shifted focus towards aeration systems optimization, due to the high energy consumption of aeration processes in modern advanced wastewater treatment plants. The activated sludge wastewater treatment process is dependent on aeration efficiency which supplies the oxygen needed in the treatment process. The process is a complex heterogeneous mixture of microorganisms, bacteria, particles, colloids, natural organic matter, polymers and cations with varying densities, shapes and sizes. These activated sludge parameters have different impacts on aeration efficiency defined by the OTE, % and alpha. Oxygen transfer efficiency (OTE) is the mass of oxygen transferred into the liquid from the mass of air or oxygen supplied, and is expressed as a percentage (%). OTE is the actual operating efficiency of an aeration system. The alpha Factor (α) is the ratio of standard oxygen transfer efficiency at process conditions (αSOTE) to standard oxygen transfer efficiency of clean water (SOTE). It is also referred to as the ratio of process water volumetric mass transfer coefficient to clean water volumetric mass transfer coefficient. The alpha factor accounts for wastewater contaminants (i.e. soap and detergent) which have an adverse effect on oxygen transfer efficiency. Understanding their different impacts and how different treatment technologies affect aeration efficiency will help to optimize and improve aeration efficiency so as to reduce plant operating costs. A pilot scale study of fine pore diffuser fouling and mitigation, quantified by dynamic wet pressure (DWP), oxygen transfer efficiency and alpha measurement were performed at Blue Plains, Washington DC. In the study a mechanical cleaning method, reverse flexing (RF), was used to treat two diffusers (RF1, RF2) to mitigate fouling, while two diffusers were kept as a control with no reverse flexing. A 45 % increase in DWP of the control diffuser after 17 month of operation was observed, an indication of fouling. RF treated diffusers (RF1 and RF2) did not show any significant increase in DWP, and in comparison to the control diffuser prevented a 35 % increase in DWP. Hence, the RF fouling mitigation technique potentially saved blower energy consumption by reducing the pressure burden on the air blower and the blower energy requirement. However, no significant impact of the RF fouling mitigation treatment technique in preventing a decrease in alpha-fouling (𝝰F) of the fine pore diffusers over time of operation was observed. This was because either the RF treatment method maintained wide pore openings after cleaning over time, or a dominant effect of other wastewater characteristics such as the surfactant concentration or particulate COD could have interfered with OTE. Further studies on the impact of wastewater characteristics (i.e., surfactants and particulate COD) and operating conditions on OTE and alpha were carried out in another series of pilot and batch scale tests. In this study, the influence of different wastewater matrices (treatment phases) on oxygen transfer efficiency (OTE) and alpha using full-scale studies at the Blue Plains Treatment Plant was investigated. A strong relationship between the wastewater matrices with oxygen transfer characteristics was established, and as expected increased alphas were observed for the cleanest wastewater matrices (i.e., with highest effluent quality). There was a 46 % increase in alpha as the total COD and surfactant concentrations decreased from 303 to 24 mgCOD/L and 12 to 0.3 mg/L measured as sodium dodecyl sulphate (SDS) in the nitrification/denitrification effluent with respect to the raw influent. The alpha improvement with respect to the decrease in COD and surfactant concentration suggested the impact of one or more of the wastewater characteristics on OTE and alpha. Batch testing conducted to characterize the mechanistic impact of the wastewater contaminants present in the different wastewater matrices found that the major contaminants influencing OTE and alpha were surfactants and particulate/colloidal material. The volumetric mass transfer coefficient (kLa) measurements from the test also identified surfactant and colloidal COD as the major wastewater contaminants present in the influent and chemically enhanced primary treatment (CEPT) effluent wastewaters impacting OTE and alpha. Soluble COD was observed to potentially improve OTE and alpha due to its contribution in enhancing the oxygen uptake rate (OUR). Although the indirect positive impact of OUR on alpha observed in this study contradicts some other studies, it shows the need for further investigation of OUR impacts on oxygen transfer. Importantly, the mechanistic characterization and quantitative correlation between wastewater contaminants and aeration efficiency found in this study will help to minimize overdesign with respect to aeration system specification, energy wastage, and hence the cost of operation. This study therefore shows new tools as well as the identification of critical factors impacting OTE and alpha in addition to diffuser fouling. Gas transfer depression caused by surfactants when they accumulate at the gas-liquid interface during the activated sludge wastewater treatment process reduces oxygen mass transfer rates, OTE and alpha which increases energy cost. In order to address the adverse effect of surfactants on OTE and alpha, another study was designed to evaluate 4 different wastewater secondary treatment strategies/technologies that enhances surfactant removal through enhanced biosorption and biodegradation, and to also determine their effect on oxygen transfer and alpha. A series of pilot and batch scale tests were conducted to compare and correlate surfactant removal efficiency and alpha for a) conventional high-rate activated sludge (HRAS), b) optimized HRAS with contactor-stabilization technology (HRAS-CS), c) optimized HRAS bioaugmented (Bioaug) with nitrification sludge (Nit S) and d) optimized bioaugmented HRAS with an anaerobic selector phase technology (An-S) reactor system configuration. The treatment technologies showed surfactant percentage removals of 37, 45, 61 and 87 %, and alphas of 0.37 ±0.01, 0.42 ±0.02, 0.44 ±0.01 and 0.60 ±0.02 for conventional HRAS, HRAS-CS, Bioaug and the An-S reactor system configuration, respectively. The optimized bioaugmented anaerobic selector phase technology showed the highest increased surfactant removal (135 %) through enhanced surfactant biosorption and biodegradation under anaerobic conditions, which also complemented the highest increased alpha (62 %) achieved when compared to the conventional HRAS. This study showed that the optimized bioaugmented anaerobic selector phase reactor system configuration is a promising technology or strategy to minimize the surfactant effects on alpha during the secondary aeration treatment stage
- Effective Modeling of Nutrient Losses and Nutrient Management Practices in an Agricultural and Urbanizing WatershedLiu, Yingmei (Virginia Tech, 2011-12-05)The Lake Manassas Watershed is a 189 km2 basin located in the Northern Virginia suburbs of Washington, DC. Lake Manassas is a major waterbody in the watershed and serves as a drinking water source for the City of Manassas. Lake Manassas is experiencing eutrophication due to nutrient loads associated with agricultural activities and urban development in its drainage areas. Two watershed model applications using HSPF, and one receiving water quality model application using CE-QUAL-W2, were linked to simulate Lake Manassas as well as its drainage areas: the Upper Broad Run (126.21 km2) and Middle Broad Run (62.79 km2) subbasins. The calibration of the linked model was for the years 2002-05, with a validation period of 2006-07. The aspects of effective modeling of nutrient losses and nutrient management practices in the Lake Manassas watershed were investigated. The study was mainly conducted in the Upper Broad Run subbasin, which was simulated with an HSPF model. For nutrient simulation, HSPF provides two algorithms: PQUAL (simple, empirically based) and AGCHEM (detailed, process-based). This study evaluated and compared the modeling capabilities and performance of PQUAL and AGCHEM, and investigated significant inputs and parameters for their application. Integral to the study was to develop, calibrate and validate HSPF/PQUAL and HSPF/AGCHEM models in the Upper Broad Run subbasin. "One-variable-at-a-time" sensitivity analysis was conducted on the calibrated Upper Broad Run HSPF/PQUAL and HSPF/AGCHEM models to identify significant inputs and parameters for nutrient load generation. The sensitivity analysis results confirmed the importance of accurate meteorological inputs and flow simulation for effective nutrient modeling. OP (orthophosphate phosphorus) and NH4-N (ammonium nitrogen) loads were sensitive to PQUAL parameters describing pollutant buildup and washoff at land surface. The significant PQUAL parameter for Ox-N (oxidized nitrogen) load was groundwater nitrate concentration. For the HSPF/AGCHEM model, fertilizer application rate and time were very important for nutrient load generation. NH4-N and OP loads were sensitive to the AGCHEM parameters describing pollutant adsorption and desorption in the soil. On the other hand, plant uptake of nitrogen played an important role for Ox-N load generation. A side by side comparison was conducted on the Upper Broad Run HSPF/PQUAL and HSPF/AGCHEM models. Both PQUAL and AGCHEM provided good-to-reasonable nutrient simulation. The comparison results showed that AGCHEM performed better than PQUAL for OP simulation, but PQUAL captured temporal variations in the NH4-N and Ox-N loads better than AGCHEM. Compared to PQUAL, AGCHEM is less user-friendly, requires a lot more model input parameters and takes much more time in model development and calibration. On the other hand, use of AGCHEM affords more model capabilities, such as tracking nutrient balances and evaluating alternative nutrient management practices. This study also demonstrated the application of HSPF/AGCHEM within a linked watershed-reservoir model system in the Lake Manassas watershed. By using the outputs generated by the HSPF/AGCHEM models in the Upper Broad Run and Middle Broad Run subbasins, the Lake Manassas CE-QUAL-W2 model adequately captured water budget, temporal and spatial distribution of water quality constituents associated with summer stratification in the lake. The linked model was used to evaluate water quality benefits of implementing nutrient management plan in the watershed. The results confirmed that without the nutrient management plan OP loads would be much higher, which would lead to OP enrichment and enhanced algae growth in Lake Manassas.
- Efficient Resource Development in Electric Utilities Planning Under UncertaintyMaricar, Noor M. (Virginia Tech, 2004-09-07)The thesis aims to introduce an efficient resource development strategy in electric utility long term planning under uncertainty considerations. In recent years, electric utilities have recognized the concepts of robustness, flexibility, and risk exposure, to be considered in their resource development strategy. The concept of robustness means to develop resource plans that can perform well for most, if not all futures, while flexibility is to allow inexpensive changes to be made if the future conditions deviate from the base assumptions. A risk exposure concept is used to quantify the risk hazards in planning alternatives for different kinds of future conditions. This study focuses on two technical issues identified to be important to the process of efficient resource development: decision-making analysis considering robustness and flexibility, and decision-making analysis considering risk exposure. The technique combines probabilistic methods and tradeoff analysis, thereby producing a decision set analysis concept to determine robustness that includes flexibility measures. In addition, risk impact analysis is incorporated to identify the risk exposure in planning alternatives. Contributions of the work are summarized as follows. First, an efficient resource development framework for planning under uncertainty is developed that combines features of utility function, tradeoff analysis, and the analytical hierarchy process, incorporating a performance evaluation approach. Second, the multi-attribute risk-impact analysis method is investigated to handle the risk hazards exposed in power system resource planning. Third, the penetration levels of wind and photovoltaic generation technologies into the total generation system mix, with their constraints, are determined using the decision-making model. The results from two case studies show the benefits of the proposed framework by offering the decision makers various options for lower cost, lower emission, better reliability, and higher efficiency plans.
- An Environmental Decision Support System to Facilitate Stakeholder Interaction with Water Quality ModelsKumar, Saurav (Virginia Tech, 2012-02-03)Environmental management has increasingly become a participatory process. In recent times, emphasis has been placed on watershed-based solutions to remediate the problems of diffuse source pollution and to engage stakeholders in designing solutions. Water quality models are an integral part of this process; such models are often inaccessible to lay stakeholders. A review of the literature suggests that properly applied partnerships have several benefits that go beyond decision-making. Stakeholder education and enhancements to the eventual outcome from stakeholder insight and support are two such benefits. To aid engineers and scientists, who often do not interact directly with other stakeholders, several best practices were identified that may be applied to develop, manage, and evaluate stakeholder partnerships. Environmental Decision Support Systems (EDSSs) have been shown to be an effective way to promote stakeholder partnerships in environmental decision-making. Many current EDSSs were designed to be used by experts, thus limiting their effectiveness for stakeholder engagement. Often, these EDSSs, if designed for lay stakeholders, were not coupled with water quality models. To demonstrate that complex water quality models may be made accessible to stakeholders, without any significant changes to the modeling scheme, a web-based EDSS was developed for the Occoquan Reservoir, located in northern Virginia, U.S.A., and its tributary watershed. The developed EDSS may also be readily extended to other watersheds and their modeling programs. The current implementation of the EDSS enables users to modify land use and analyze simulated changes to water quality due to these modifications. A local-network server cluster, based on the Locally Distributed Simultaneous Model Execution (LDSME) framework, was also developed and served as a backend to the EDSS. The server cluster can support simultaneous execution of multiple water quality models or any other software on disparate computers. This system was employed to study pre-development and other land use modification scenarios in the Occoquan Watershed. The pre-development scenario offers an easy-to-understand and universally-applicable baseline for measuring waterbody and watershed restoration progress. It enabled computation of a measure called the "developed-excess," which is independent of local conditions and may be used for comparisons among various watershed sub-divisions or between watersheds.