Di-μ2-chlorido-bis-[chlorido(η(5)-2,3,4,5-tetra-methyl-1-propyl-cyclo-penta-dien-yl)iridium(III)]

Simple item page
dc.contributor.authorMerola, Joseph S.en
dc.contributor.authorMorris, Daviden
dc.contributor.authorDe Weerd, Nicholasen
dc.contributor.departmentChemistryen
dc.coverage.spatialUnited Statesen
dc.date.accessioned2016-09-22T15:19:12Zen
dc.date.available2016-09-22T15:19:12Zen
dc.date.issued2013-03-01en
dc.description.abstractThe asymmetric unit of the title complex, [Ir2Cl4(C12H19)2], a versatile starting material for the preparation of uniquely substituted penta-alkyl-cyclo-penta-dien-yl-iridium complexes, consists of an iridium(III) atom, a substituted cyclo-penta-dienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two Ir(III) atoms and two bridging Cl atoms form a perfectly planar ring. The two Ir(III) atoms and the two terminal Cl atoms also form a rigorous plane that is orthogonal [89.48 (3)°] to the Ir2Cl2 ring. The plane of the cyclo-penta-dienyl ligand forms a dihedral angle of 54.06 (7)° with respect to the Ir2Cl2 ring.en
dc.description.versionPublished versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationActa Cryst. (2013). E69, m176 [ doi:10.1107/S1600536813005072 ]en
dc.identifier.doihttps://doi.org/10.1107/S1600536813005072en
dc.identifier.eissn1600-5368en
dc.identifier.issuePt 3en
dc.identifier.urihttp://hdl.handle.net/10919/73019en
dc.identifier.volume69en
dc.language.isoenen
dc.publisherInternational Union of Crystallographyen
dc.relation.ispartofseriesActa Crystallographica Section E: Structure Reports Online;en
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/23476515en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectiridiumen
dc.subjectcyclopentadienylen
dc.subjectx-rayen
dc.subjectcrystalen
dc.subjectstructureen
dc.titleDi-μ2-chlorido-bis-[chlorido(η(5)-2,3,4,5-tetra-methyl-1-propyl-cyclo-penta-dien-yl)iridium(III)]en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Di-μ2-chlorido-bis-[chlorido(η(5)-2,3,4,5-tetra-methyl-1-propyl-cyclo-penta-dien-yl)iridium(III)].pdf
Size:
304.13 KB
Format:
Adobe Portable Document Format
Description:
Publisher's Version
Download
License bundle
Now showing 1 - 1 of 1
Name:
VTUL_Distribution_License_2016_05_09.pdf
Size:
18.09 KB
Format:
Adobe Portable Document Format
Description:
Download

Collections

All Faculty Deposits
Scholarly Works, Chemistry