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Bis[bis-(penta-methyl-cyclo-penta-dien-yl)cobalt(III)] tetra-chlorido-cobaltate(II) di-chloro-methane disolvate.

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dc.contributor.authorMerola, Joseph S.en
dc.contributor.authorNgo, Maien
dc.contributor.authorKarpin, George W.en
dc.contributor.departmentChemistryen
dc.coverage.spatialUnited Statesen
dc.date.accessioned2016-09-22T15:15:43Zen
dc.date.available2016-09-22T15:15:43Zen
dc.date.issued2013en
dc.description.abstractThe title compound, [Co(C10H15)2]2[CoCl4]ยท2CH2Cl2, was isolated as a dichloromethane solvate and was formed in the reaction between lithium pentamethylcyclopentadienide and anyhydrous cobalt(II) chloride in tetrahydrofuran. There are two decamethylcobaltocenium cations, one tetrachloridocobaltate(II) anion and two dichloromethane solvent molecules in the formula unit. There is a slight disorder of the dichloromethane solvent which was treated with a two-site model [occupancy rates = 0.765 (4) and 0.235 (4)]. The dichloromethane molecules display significant C-HCl interactions with the tetrachloridocobaltate(II) dianion. The cobalt atom of the decamethylcobaltocenium cation sits on a twofold rotation axis, with only one pentamethylcyclopentadiene ligand being unique and the second generated by symmetry. The cobalt atom of the [CoCl4]-2 ion sits on a special site with -4 symmetry, with one unique chloride ligand and the others generated by the fourfold inversion axis.en
dc.description.versionPublished versionen
dc.format.extentm504 - ? page(s)en
dc.identifier.citationActa Cryst. (2013). E69, m504 [doi:10.1107/S160053681302254X ]en
dc.identifier.doihttps://doi.org/10.1107/S160053681302254Xen
dc.identifier.eissn1600-5368en
dc.identifier.issuePt 9en
dc.identifier.urihttp://hdl.handle.net/10919/73015en
dc.identifier.volume69en
dc.languageengen
dc.publisherInternational Union of Crystallographyen
dc.relation.ispartofseriesActa Crystallographica Section E: Structure Reports Online;en
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/24426998en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectCobalten
dc.subjectsolvateen
dc.subjecthydrogen bondingen
dc.subjectx-rayen
dc.subjectcrystal structureen
dc.titleBis[bis-(penta-methyl-cyclo-penta-dien-yl)cobalt(III)] tetra-chlorido-cobaltate(II) di-chloro-methane disolvate.en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen

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