Elaboration of micelle formation in aqueous and two phase solutions by surface active phosphines

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dc.contributor.authorBarnes, Jeffery G.en
dc.contributor.committeechairHanson, Brian E.en
dc.contributor.committeememberBrewer, Karen J.en
dc.contributor.committeememberAnderson, Mark R.en
dc.contributor.departmentChemistryen
dc.date.accessioned2014-03-14T21:38:03Zen
dc.date.adate2009-06-11en
dc.date.available2014-03-14T21:38:03Zen
dc.date.issued1995-12-17en
dc.date.rdate2009-06-11en
dc.date.sdate2009-06-11en
dc.description.abstractThe surface active phosphine ((C6H4))C3H6((C6H4)S03 N+)3,1, aggregates in aqueous solution to form micelles. Light scattering experiments were used to determine the hydrodynamic radius of the aggregates. Fluorescence, conductivity, and surface tension experiments were used to measure the critical micelle concentration of these aggregates. Fluorescence experiments, using a quencher and probe analysis, show the number of particles per aggregate. Nuclear Magnetic Resonance (NMR) shows that these micelles are able to incorporate olefin within the hydrophobic region and are acting as phase transfer agents.en
dc.description.degreeMaster of Scienceen
dc.format.extentvi, 73 leavesen
dc.format.mediumBTDen
dc.format.mimetypeapplication/pdfen
dc.identifier.otheretd-06112009-063728en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-06112009-063728/en
dc.identifier.urihttp://hdl.handle.net/10919/43181en
dc.language.isoenen
dc.publisherVirginia Techen
dc.relation.haspartLD5655.V855_1995.B3683.pdfen
dc.relation.isformatofOCLC# 34609523en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjectmicelleen
dc.subjectphosphineen
dc.subjectchemistryen
dc.subjectcatalysisen
dc.subjecttwo phaseen
dc.subject.lccLD5655.V855 1995.B3683en
dc.titleElaboration of micelle formation in aqueous and two phase solutions by surface active phosphinesen
dc.typeThesisen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemistryen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.levelmastersen
thesis.degree.nameMaster of Scienceen

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