(S)-α-Benzylprolinium cis-[(S)-α-benzyl-prolinato]dichloridopalladium(II)
dc.contributor.author | Hobart, David B. Jr. | en |
dc.contributor.author | Merola, Joseph S. | en |
dc.contributor.department | Chemistry | en |
dc.coverage.spatial | United States | en |
dc.date.accessioned | 2016-09-22T15:17:16Z | en |
dc.date.available | 2016-09-22T15:17:16Z | en |
dc.date.issued | 2013-04-13 | en |
dc.description.abstract | The title complex salt, (C12H16NO2)[PdCl2(C12H14NO2)], is of inter-est with respect to organic and organometallic catalysis. The compound crystallizes as very small orange-red irregular prisms and the asymmetric unit contains three crystallographically distinct cation-anion pairs. The coordination geometry about the palladium atoms is square-planar with the chloride ligands cis to one another. The structure displays N-H⋯Cl and O-H⋯O hydrogen bonding such that the N-H⋯Cl hydrogen bonds align the cation-anion pairs in a linear fashion along [001], with the O-H⋯O hydrogen bonds connecting these linear strands along [100] and [010]. | en |
dc.description.version | Published version | en |
dc.format.extent | m261 - m262 page(s) | en |
dc.format.mimetype | application/pdf | en |
dc.identifier.citation | Acta Cryst. (2013). E69, m261-m262 [doi:10.1107/S1600536813009525] | en |
dc.identifier.doi | https://doi.org/10.1107/S1600536813009525 | en |
dc.identifier.eissn | 1600-5368 | en |
dc.identifier.issue | Pt 5 | en |
dc.identifier.uri | http://hdl.handle.net/10919/73017 | en |
dc.identifier.volume | 69 | en |
dc.language.iso | en | en |
dc.publisher | International Union of Crystallography | en |
dc.relation.uri | http://www.ncbi.nlm.nih.gov/pubmed/23723771 | en |
dc.rights | Creative Commons Attribution 4.0 International | en |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | en |
dc.subject | crystal structure | en |
dc.subject | x-ray | en |
dc.subject | palladium | en |
dc.subject | amino acids | en |
dc.title | (S)-α-Benzylprolinium cis-[(S)-α-benzyl-prolinato]dichloridopalladium(II) | en |
dc.title.serial | Acta Crystallographica Section E: Structure Reports Online | en |
dc.type | Article - Refereed | en |
dc.type.dcmitype | Text | en |
pubs.organisational-group | /Virginia Tech | en |
pubs.organisational-group | /Virginia Tech/All T&R Faculty | en |
pubs.organisational-group | /Virginia Tech/Faculty of Health Sciences | en |
pubs.organisational-group | /Virginia Tech/Science | en |
pubs.organisational-group | /Virginia Tech/Science/Chemistry | en |
pubs.organisational-group | /Virginia Tech/Science/COS T&R Faculty | en |
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