In situ ¹³C NMR monitoring of the dehydration of 2-propanol over H-ZSM-5

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dc.contributor.authorMorgan, David Reesen
dc.contributor.departmentChemistryen
dc.date.accessioned2015-05-08T19:38:51Zen
dc.date.available2015-05-08T19:38:51Zen
dc.date.issued1989en
dc.description.abstractThe first <i>in situ</i> ¹³C NMR monitoring of zeolite catalyzed reaction is described. The dehydration of 2-propanol over H-ZSM-5 was observed using solution type techniques. Although this produces broad lines, several mechanistic details were elucidated. This study indicates that: 1) the dehydration does not proceed through a cyclopropyl carbenium ion intermediate, 2) propene oligomerizes on the catalyst and reaches a steady state concentration before propene is desorbed, and 3) the 2-propanol flowing over the catalyst does not react with the oligomerized propene.en
dc.description.degreeMaster of Scienceen
dc.format.extentviii, 72 leavesen
dc.format.mimetypeapplication/pdfen
dc.identifier.urihttp://hdl.handle.net/10919/52091en
dc.language.isoen_USen
dc.publisherVirginia Polytechnic Institute and State Universityen
dc.relation.isformatofOCLC# 19782035en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V855 1989.M673en
dc.subject.lcshCatalysts -- Analysisen
dc.subject.lcshZeolites -- Analysisen
dc.titleIn situ ¹³C NMR monitoring of the dehydration of 2-propanol over H-ZSM-5en
dc.typeThesisen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemistryen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.levelmastersen
thesis.degree.nameMaster of Scienceen

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