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Review of the Research Status of Cost-Effective Zinc-Iron Redox Flow Batteries

dc.contributor.authorZhang, Huanen
dc.contributor.authorSun, Chuanyuen
dc.contributor.authorGe, Mingmingen
dc.date.accessioned2022-11-10T18:42:40Zen
dc.date.available2022-11-10T18:42:40Zen
dc.date.issued2022-10-31en
dc.date.updated2022-11-10T14:27:24Zen
dc.description.abstractZinc–iron redox flow batteries (ZIRFBs) possess intrinsic safety and stability and have been the research focus of electrochemical energy storage technology due to their low electrolyte cost. This review introduces the characteristics of ZIRFBs which can be operated within a wide pH range, including the acidic ZIRFB taking advantage of Fen+ with high solubility, the alkaline ZIRFB operating at a relatively high open-circuit potential and current densities, and the neutral ZIRFB providing a non-toxic, harmless, and mild environment. No matter what kind of ZIRFB, there are always zinc dendrites limiting areal capacity on the anode, which has become an obstacle that must be considered in zinc-based RFBs. Therefore, we focus on the current research progress, especially the summarizing and analysis of zinc dendrites, Fe(III) hydrolysis, and electrolytes. Given these challenges, this review reports the optimization of the electrolyte, electrode, membrane/separator, battery structure, and numerical simulations, aiming to promote the performance and development of ZIRFBs as a practical application technology. Based on these investigations, we also provide the prospects and development direction of ZIRFBs.en
dc.description.versionPublished versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationZhang, H.; Sun, C.; Ge, M. Review of the Research Status of Cost-Effective Zinc-Iron Redox Flow Batteries. Batteries 2022, 8, 202.en
dc.identifier.doihttps://doi.org/10.3390/batteries8110202en
dc.identifier.urihttp://hdl.handle.net/10919/112561en
dc.language.isoenen
dc.publisherMDPIen
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectzinc–ironen
dc.subjectredox flow batteryen
dc.subjectcost-effectiveen
dc.subjectzinc dendriteen
dc.subjectelectrolyte designen
dc.subjection-exchange membraneen
dc.subjectlarge-scale energy storageen
dc.titleReview of the Research Status of Cost-Effective Zinc-Iron Redox Flow Batteriesen
dc.title.serialBatteriesen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten

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