Processing of composite fibers based on polypropylene and a thermotropic liquid crystalline polymer

dc.contributor.authorRobertson, Christopher G.en
dc.contributor.departmentChemical Engineeringen
dc.date.accessioned2014-03-14T21:27:24Zen
dc.date.adate2009-01-17en
dc.date.available2014-03-14T21:27:24Zen
dc.date.issued1995en
dc.date.rdate2009-01-17en
dc.date.sdate2009-01-17en
dc.description.abstractIsotactic polypropylene (PP) was reinforced with Vectra B950 (VB), a thermotropic liquid crystalline polymer (TLCP), in two novel fiber spinning processes. In one process, a single VB melt stream was surrounded by a sheath of PP in a manner comparable to a wire coating process just prior to melt spinning to generate fibers possessing a sheath-core structure. The other process involved the distribution of continuous VB melt streams within a separately plasticated PP melt to form a composite melt which was drawn to create matrix-fibril fibers consisting of a PP matrix in situ reinforced with VB fibrils. Both processes allow polymers with non-overlapping processing temperatures to be combined and melt spun to form composite fibers. The effect of fiber draw ratio on the tensile mechanical properties was assessed for composite fibers reinforced with 50 wt.% (39 vol.%) VB. Numerical simulations of the non-isothermal fiber drawing processes and an investigation of fiber morphology were undertaken in order to explain the mechanical properties. The matrix-fibril (in situ) reinforced fibers were woven into fabric preforms. The preforms, pre-wetted with PP, were used to fabricate orthotropic composites, and the mechanical performance and formability of these composites was evaluated.en
dc.description.degreeMaster of Scienceen
dc.format.extentxiii, 175 leavesen
dc.format.mediumBTDen
dc.format.mimetypeapplication/pdfen
dc.identifier.otheretd-01172009-063538en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-01172009-063538/en
dc.identifier.urihttp://hdl.handle.net/10919/40661en
dc.language.isoenen
dc.publisherVirginia Techen
dc.relation.haspartLD5655.V855_1995.R629.pdfen
dc.relation.isformatofOCLC# 34424797en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V855 1995.R629en
dc.titleProcessing of composite fibers based on polypropylene and a thermotropic liquid crystalline polymeren
dc.typeThesisen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemical Engineeringen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.levelmastersen
thesis.degree.nameMaster of Scienceen

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