The oxidation of ilmenite: a kinetic study
dc.contributor.author | Corsa, Lawrence J. | en |
dc.contributor.department | Materials Engineering | en |
dc.date.accessioned | 2015-04-29T18:10:07Z | en |
dc.date.available | 2015-04-29T18:10:07Z | en |
dc.date.issued | 1977 | en |
dc.description.abstract | Synthetically obtained ilmenite (FeO·TiO₂) particles were oxidized under conditions of a non-linear temperature increase over the range 300°-850°C. Short-circuit diffusion in the initial stages of oxidation gave an activation energy of 4.35 ± 0.4 kcal/mole, while above 525°C the activation energy was 50.2 ± 3.0 kcal/mole. The process was shown to be diffusion controlled, with iron the likely mobile species above 525°C, while no mechanism could be singled out for the controlling step in the early stages. The oxidation products in O₂ after 24 hours were shown to be pseudorutile (Fe₂Ti₃O₉) and hematite (Fe₂O₃) in a finely dispersed phase at temperatures below about 800°C, with pseudobrookite (Fe₂TiO₅) and rutile (TiO₂) being stable above this temperature. | en |
dc.description.degree | Master of Science | en |
dc.format.extent | 71 leaves | en |
dc.format.mimetype | application/pdf | en |
dc.identifier.uri | http://hdl.handle.net/10919/51887 | en |
dc.language.iso | en_US | en |
dc.publisher | Virginia Polytechnic Institute and State University | en |
dc.relation.isformatof | OCLC# 8145757 | en |
dc.rights | In Copyright | en |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | en |
dc.subject.lcc | LD5655.V855 1977.C675 | en |
dc.subject.lcsh | Ilmenite | en |
dc.subject.lcsh | Oxidation | en |
dc.title | The oxidation of ilmenite: a kinetic study | en |
dc.type | Thesis | en |
dc.type.dcmitype | Text | en |
thesis.degree.discipline | Materials Engineering | en |
thesis.degree.grantor | Virginia Polytechnic Institute and State University | en |
thesis.degree.level | masters | en |
thesis.degree.name | Master of Science | en |
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