The oxidation of ilmenite: a kinetic study

dc.contributor.authorCorsa, Lawrence J.en
dc.contributor.departmentMaterials Engineeringen
dc.date.accessioned2015-04-29T18:10:07Zen
dc.date.available2015-04-29T18:10:07Zen
dc.date.issued1977en
dc.description.abstractSynthetically obtained ilmenite (FeO·TiO₂) particles were oxidized under conditions of a non-linear temperature increase over the range 300°-850°C. Short-circuit diffusion in the initial stages of oxidation gave an activation energy of 4.35 ± 0.4 kcal/mole, while above 525°C the activation energy was 50.2 ± 3.0 kcal/mole. The process was shown to be diffusion controlled, with iron the likely mobile species above 525°C, while no mechanism could be singled out for the controlling step in the early stages. The oxidation products in O₂ after 24 hours were shown to be pseudorutile (Fe₂Ti₃O₉) and hematite (Fe₂O₃) in a finely dispersed phase at temperatures below about 800°C, with pseudobrookite (Fe₂TiO₅) and rutile (TiO₂) being stable above this temperature.en
dc.description.degreeMaster of Scienceen
dc.format.extent71 leavesen
dc.format.mimetypeapplication/pdfen
dc.identifier.urihttp://hdl.handle.net/10919/51887en
dc.language.isoen_USen
dc.publisherVirginia Polytechnic Institute and State Universityen
dc.relation.isformatofOCLC# 8145757en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V855 1977.C675en
dc.subject.lcshIlmeniteen
dc.subject.lcshOxidationen
dc.titleThe oxidation of ilmenite: a kinetic studyen
dc.typeThesisen
dc.type.dcmitypeTexten
thesis.degree.disciplineMaterials Engineeringen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.levelmastersen
thesis.degree.nameMaster of Scienceen

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