Part I, Preliminary investigation of one-hundred organic compounds as possible colorimetric reagents ; Part II, Solubility of the alkaline earth salts of some higher fatty acids

dc.contributor.authorKemp, Benjamin H.en
dc.contributor.departmentChemistryen
dc.date.accessioned2022-05-24T17:21:43Zen
dc.date.available2022-05-24T17:21:43Zen
dc.date.issued1940en
dc.description.abstractWe may summarize the purposes of this investigation as follows: A report on this investigation was made to Dr. John H. Yoe of the University of Virginia in order to see what reactions he considered to be of analytical significance and should be further investigated. He considers only three to be of any practical importance. They are as follows: 1. 7A-Oleic Acid. Solubility of the alkaline earth salts of some higher fatty acids. 2. 69A- 2-Acetamino 6-Aminobenzo Thiazole. A colorimetric reagent for iridium. 3. 71A 2-Hydroxy 3-Nitro 5-Sulfobenzoic Acid. A colorimetric reagent for ferric iron. A further investigation of compound 71A, as a colorimetric reagent for ferric iron, reveals that the sensitivity of this reaction is not great enough for it to be of any practical importance, since we have reagents (2) for this ion that are several times more sensitive. Prospective reagent No. 69A for iridium is being further investigated by Mr. J. R. Noell (1). A report on 7A will be taken up in Part II of this thesis. 1. It has been shown that there is very little difference in the solubility of the same alkaline earth salt of stearic, oleic, linoleic, and linolenic acids in the solvents, water, benzene, absolute ethyl alcohol and ether. 2. It has been shown that there is very little difference in the solubility of the different alkaline earth salt of stearic, oleic, linoleic, and linolenic acids in the solvents, water, benzene, absolute ethyl alcohol and ether, and benzene. 3. The solubility of the alkaline earth salt of these acids increases slightly with unsaturation, but does not increase as the degree of unsaturation increases.en
dc.description.degreeM.S.en
dc.format.extent4 unnumbered pages, 38 leavesen
dc.format.mimetypeapplication/pdfen
dc.identifier.urihttp://hdl.handle.net/10919/110219en
dc.language.isoenen
dc.publisherVirginia Agricultural and Mechanical College and Polytechnic Instituteen
dc.relation.isformatofOCLC# 30387296en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V855 1940.K467en
dc.subject.lcshAlkaline earth metals -- Solubilityen
dc.subject.lcshColorimetric analysisen
dc.subject.lcshOrganic compoundsen
dc.titlePart I, Preliminary investigation of one-hundred organic compounds as possible colorimetric reagents ; Part II, Solubility of the alkaline earth salts of some higher fatty acidsen
dc.typeThesisen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemistryen
thesis.degree.grantorVirginia Agricultural and Mechanical College and Polytechnic Instituteen
thesis.degree.levelmastersen
thesis.degree.nameM.S.en

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