The reaction of monochloromethyl ether with organometallic compounds

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dc.contributor.authorTang, Philip Jen-chienen
dc.contributor.departmentChemistryen
dc.date.accessioned2021-08-06T17:23:32Zen
dc.date.adate2010-07-10en
dc.date.available2021-08-06T17:23:32Zen
dc.date.issued1953en
dc.date.rdate2010-07-10en
dc.date.sdate2010-07-10en
dc.description.abstract1. The reactions of monochlormethyl ether with the magnesium cadmium and zinc derivatives of normal propyl and isopropyl halides were investigated. 2. In both the normal propyl and iso-propyl aeries, the yields of the expected condensation products RCH₂OCH₃ appeared in the order RMgX>R₂Zn>R₂Cd. 3. The primary organometallic compounds reacted with monochlormethyl ether in higher yields than did the corresponding secondary compounds. 4. A new method was developed for preparing a zinc-copper couple by heating a mixture of zinc dust and powdered cupric citrate under an atmosphere of nitrogen. 5. This method gave a couple superior in laboratory use to the zinc-copper couples how generally employed.en
dc.description.degreeMaster of Scienceen
dc.format.mediumBTDen
dc.identifier.otheretd-07102010-020021en
dc.identifier.sourceurlhttp://scholar.lib.vt.edu/theses/available/etd-07102010-020021/en
dc.identifier.urihttp://hdl.handle.net/10919/104591en
dc.publisherVirginia Techen
dc.relation.haspartLD5655.V855_1953.T363.pdfen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjectOrganometallic compounds.en
dc.subject.lccLD5655.V855 1953.T363en
dc.titleThe reaction of monochloromethyl ether with organometallic compoundsen
dc.typeThesisen
thesis.degree.disciplineChemistryen
thesis.degree.grantorVirginia Polytechnic Instituteen
thesis.degree.levelmastersen
thesis.degree.nameMaster of Scienceen

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