Economic Potential of Rare Earth Elements Within Accessory Minerals of Granitic Pegmatite Mine Tailings

dc.contributor.authorKegley, Dalton Curtisen
dc.contributor.committeechairCaddick, Mark J.en
dc.contributor.committeememberBodnar, Robert J.en
dc.contributor.committeememberJohnson, Neil Evanen
dc.contributor.departmentGeosciencesen
dc.date.accessioned2021-07-01T08:00:57Zen
dc.date.available2021-07-01T08:00:57Zen
dc.date.issued2021-06-29en
dc.description.abstractRare Earth elements (REEs) are economically important due to their critical applications within multiple industries. This study investigates the Spruce Pine district of North Carolina, testing the economic feasibility of repurposing current mine waste tailings as a rare earth element resource. Spruce Pine is home to several active quartz and feldspar mining operations, with large waste tailing piles generated during the separation process for quartz and feldspar. The mineralogy, composition, and REE budget of the tailings was examined to assess the economic viability of rare earth element extraction. The local geology includes a series of muscovite class pegmatites of Devonian age (390 Ma), intruded into the primarily amphibolite-grade units of the Ashe and Alligator Back formations (Wood, 1996). The waste tailing piles of two on-going quartz mining operations were sampled to evaluate the potential economic feasibility of rare earth element extraction from key accessory phases, including apatite, remaining from the initial separation process. Sample characterization utilized laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), X-ray fluorescence (XRF), energy-dispersive X-ray spectrometry (EDS), and X-ray diffraction (XRD). The results of this investigation support the conclusion that, at the current recovery rate, price of rare earth elements, and cost of refinement, economic recovery of REE from the studied tailings is not viable. However, yttrium and dysprosium offer the highest potential for economic recovery. If some combination of improvements to the extraction process, reduction in refinement cost, or increases in price occur, yttrium and dysprosium are sufficiently abundant that extraction could become economically viable.en
dc.description.abstractgeneralRare Earth elements (REEs) are comprised of the Lanthanide series of elements as well as yttrium and scandium. REEs are economically important due to their critical applications within multiple industries. Current uses include electronics, magnets, lasers, electric motors, optical fibers, nuclear reactor control rods, visual displays, etc. Although the demand for REEs is high, the current sourcing of REEs is quite scarce. This study investigates the Spruce Pine district of North Carolina, testing the economic feasibility of repurposing current mine waste tailings as a rare earth element resource. Spruce Pine is home to several active quartz and feldspar mining operations, with large waste tailing piles generated during the separation process for quartz and feldspar. The mineralogy, composition and REE budget of the tailings was examined to assess the economic viability of rare earth element extraction. The waste tailing piles of two on-going quartz mining operations were sampled to evaluate the potential economic feasibility of rare earth element extraction from key accessory phases, including apatite, remaining from the initial separation process. The results of this investigation support the conclusion that, at the current recovery rate, price of rare earth elements, and cost of refinement, economic recovery of REE from the studied tailings is not viable. However, yttrium and dysprosium offer the highest potential for economic recovery. If some combination of improvements to the extraction process, reduction in cost of refinement, or increase in price were to occur, yttrium and dysprosium are sufficiently abundant that extraction could become economically viable.en
dc.description.degreeMaster of Scienceen
dc.format.mediumETDen
dc.identifier.othervt_gsexam:30241en
dc.identifier.urihttp://hdl.handle.net/10919/104065en
dc.publisherVirginia Techen
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subjectRare earth elementsen
dc.subjectPegmatitesen
dc.subjectMine tailingsen
dc.subjectEconomic feasibilityen
dc.subjectSpruce Pineen
dc.subjectNorth Carolinaen
dc.titleEconomic Potential of Rare Earth Elements Within Accessory Minerals of Granitic Pegmatite Mine Tailingsen
dc.typeThesisen
thesis.degree.disciplineGeosciencesen
thesis.degree.grantorVirginia Polytechnic Institute and State Universityen
thesis.degree.levelmastersen
thesis.degree.nameMaster of Scienceen

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