Studies in the synthesis of n-butyl strontium

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dc.contributor.authorKuck, John F. R.en
dc.contributor.departmentChemistryen
dc.date.accessioned2022-05-24T17:21:43Zen
dc.date.available2022-05-24T17:21:43Zen
dc.date.issued1940en
dc.description.abstract1. Strontium does not easily react with n-butyl bromide in ether or benzene to produce an organostrontium compound. Strontium amalgam reacts to give a trace of the butyl mercury compound, perhaps through the formation of an organostrontium compound as intermediate. 2. The conversion, 2BuLi + SrCl₂ = 2LiCl + Bu₂Sr, seems to proceed predominantly to the left, perhaps because of relative solubilities of the lithium and strontium halides in the solvents used. 3. The conversion, Bu₂Hg + Sr = Hg + Bu₂Sr, appears to proceed to a slight extent to the right. So far, this reaction seems to offer the most promise in synthesizing an organostrontium compound.en
dc.description.degreeM.S.en
dc.format.extent5 unnumbered pages, 19 pages, 2 unnumbered leavesen
dc.format.mimetypeapplication/pdfen
dc.identifier.urihttp://hdl.handle.net/10919/110220en
dc.language.isoenen
dc.publisherVirginia Agricultural and Mechanical College and Polytechnic Instituteen
dc.relation.isformatofOCLC# 30053413en
dc.rightsIn Copyrighten
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.lccLD5655.V855 1940.K835en
dc.subject.lcshStrontiumen
dc.titleStudies in the synthesis of n-butyl strontiumen
dc.typeThesisen
dc.type.dcmitypeTexten
thesis.degree.disciplineChemistryen
thesis.degree.grantorVirginia Agricultural and Mechanical College and Polytechnic Instituteen
thesis.degree.levelmastersen
thesis.degree.nameM.S.en

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