VTechWorks Repository :: Browsing by Author "Boreyko, Jonathan B."

Browsing by Author "Boreyko, Jonathan B."

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Adsorption of Small Molecules in Advanced Material Systems
Zhang, Fei (Virginia Tech, 2019-06-10)
Adsorption is a ubiquitous phenomenon that plays key roles in numerous applications including molecule separation, energy storage, catalysis, and lubrications. Since adsorption is sensitive to molecular details of adsorbate molecule and adsorbent materials, it is often difficult to describe theoretically. Molecular modeling capable of resolving physical processes at atomistic scales is an effective method for studying adsorption. In this dissertation, the adsorption of small molecules in three emerging materials systems: porous liquids, room-temperature ionic liquids, and atomically sharp electrodes immersed in aqueous electrolytes, are investigated to understand the physics of adsorption as well as to help design and optimize these materials systems. Thermodynamics and kinetics of gas storage in the recently synthesized porous liquids (crown-ether-substituted cage molecules dispersed in an organic solvent) were studied. Gas molecules were found to store differently in cage molecules with gas storage capacity per cage in the following order: CO2>CH4>N2. The cage molecules show selectivity of CO2 over CH4/N2 and demonstrate capability in gas separation. These studies suggest that porous liquids can be useful for CO2 capture from power plants and CH4 separation from shale gas. The effect of adsorbed water on the three-dimensional structure of ionic liquids [BMIM][Tf2N] near mica surfaces was investigated. It was shown that water, as a dielectric solvent and a molecular liquid, can alter layering and ordering of ions near mica surfaces. A three-way coupling between the self-organization of ions, the adsorption of interfacial water, and the electrification of the solid surfaces was suggested to govern the structure of ionic liquid near solid surfaces. The effects of electrode charge and surface curvature on adsorption of N2 molecules near electrodes immersed in water were studied. N2 molecules are enriched near neutral electrodes. Their enrichment is enhanced as the electrode becomes moderately charged but is reduced when the electrode becomes highly charged. Near highly charged electrodes, the amount of N2 molecules available for electrochemical reduction is an order of magnitude higher near spherical electrodes with radius ~1nm than near planar electrodes. The underlying molecular mechanisms are elucidated and their implications for development of electrodes for electrochemical reduction of N2 are discussed.
Adsorption-Mediated Fluid Transport at the Nanoscale
Moh, Do Yoon (Virginia Tech, 2022-04-20)
Injecting CO2 into unconventional reservoirs to enhance oil recovery has been widely studied due to its potential to improve the profitability of these reservoirs. CO2 Huff-n-Puff is emerging as a promising method, but exploiting its full potential is challenging due to difficulties in optimizing its operations. The latter arises from the limited understanding of CO2 and oil transport in unconventional reservoirs. This dissertation used molecular dynamics simulations to study the storage and transport of oil and CO2 in unconventional reservoirs in single nanopores. The first study examined the modulation of oil flow in calcite pores by CO2. It is discovered that CO2 molecules adsorb strongly on calcite walls and can change decane permeability through 8 nm-wide pores by up to 30%. They impede decane flow at moderate adsorption density but enhance flow as adsorption approaches saturation. The second study investigated the CO2 transport in 4 nm-wide calcite pores during the soaking phase of Huff-n-Puff operations. CO2 entering the pore can become adsorbed on pore walls and diffuse on them or diffuse as free CO2 molecules. The accumulation of CO2 follows a diffusion behavior with an effective diffusivity ~50% smaller than bulk CO2. Two dimensionless groups are proposed to gauge the importance of surface adsorption and diffusion in CO2 storage and transport in nanopores. The third study examined the extraction of decane initially sealed in a 4 nm-wide calcite pore through exchange with CO2 and CH4 in a reservoir. The CO2-decane exchange is significantly driven by the evolution of adsorbed oil and gas initially, but a transition to dominance by free oil and gas occurs later; for CH4-decane exchange, the opposite occurs. The net gas accumulation and decane extraction follow the diffusive law, but their effective diffusivities do not always align well with the self-diffusion coefficients of CO2, CH4, and decane in the nanopore. The three studies identified the essential roles of gas/oil adsorption in their net transport in nanopores and, thus, unconventional reservoirs. Delineating these roles and formulating dimensionless groups to gauge their importance help develop better models for enhanced oil recovery from unconventional reservoirs by CO2 injection.
Advanced Thermal Management Strategies – Scalable Coal-Graphene based TIMs and Additively Manufactured Heat Sinks
Bharadwaj, Bharath Ramesh (Virginia Tech, 2022-06-27)
With increased focus on miniaturization and high performance in electronics, thermal management is a very important area of research today. In multiple applications such as portable electronics, consumer electronics, military applications, automobile, power electronics, high performance computing, etc. innovative thermal management strategies are necessary. In this work, two novel approaches to dissipate redundant heat better- first by novel carbonaceous-nanoparticle additives to develop thermal interface materials with superior performance and the second by using advanced metal additive manufacturing techniques to design and analyze metal-lattice based heat sinks are presented. Thermal Interface Materials with multiple carbon-based nanoparticle fillers such as coal-derived Multi Layered Graphene (MLG), standard reduced Graphene Oxide (rGO), Multi-Walled Carbon Nano Tubes (MWCNTs), and Graphene Nano-Platelets (GNPs) in thermal paste were synthesized and seen to have superior heat dissipation properties. Also, graphene was synthesized from coal through an in-house, facile, scalable and cost-effective process. The enhancement in thermal conductance varies from ~70% in the coal-MLG to ~14% in MWCNTs-based TIMs. Noteworthy is ~3.5 times larger enhancement in thermal performance with the in-house coal-derived-MLG as compared to the commercially available g-MLG. At a 3% wt. fraction of coal-MLG, enhancement in thermal conductance was almost 120% higher compared to the base thermal grease. In the second part, metal lattice-based heat sinks are designed for additive manufacturing for use in passive cooling of high-flux thermal management. A parametric optimization based on the lattice geometry, thickness, and height subject to additive manufacturing constraints is conducted. Intricate metal lattices with low mass based on the Simple Cubic, Octet, and Voronoi structures were generated by implicit modelling in nTopology® and their thermal performance was analyzed through numerical analysis using commercial CFD packages. The Voronoi lattice performed best with a significant improvement in thermal performance (~18% reduction in junction temperature difference with respect to ambient) as compared to a standard baseline Longitudinal heat Sink (LHS), while reducing the mass of the heat sink by ~2.1 times. Such optimized metal lattice-based heat sinks can lead to significant downsizing, reduction in overall mass and cost in applications where thermal management is critical with a need for low mass. We believe that such novel scalable materials and processes suited for mass production could be critical in meeting the material, design and product development needs to tackle the thermal management challenges of the future.
Anisotropy of Passive and Active Rat Vagina under Biaxial Loading
Huntington, Alyssa Joan (Virginia Tech, 2018-06-11)
Pelvic organ prolapse, the decent of the pelvic organs from their normal anatomical position, is a common condition among women that is associated with mechanical alterations of the vaginal wall. In order to characterize the complex mechanical behavior of the vagina, we performed planar biaxial tests of vaginal specimens in both the passive (relaxed) and active (contracted) states. Specimens were isolated from virgin, female Long-Evans rats (n=16) and simultaneously stretched along the longitudinal direction (LD) and circumferential direction (CD) of the vagina. Tissue contraction was induced by electric field stimulation (EFS) at incrementally increasing values of stretch and, subsequently, by KCl. On average, the vagina was stiffer in the CD than in the LD (p<0.001). The mean maximum EFS-induced active stress was significantly higher in the CD than in the LD (p<0.001). On the contrary, the mean KCl-induced active stress was lower in the CD than in the LD (p<0.01). When comparing the mean maximum EFS-induced active stress to the mean KCl-induced active stress, no differences were found in the CD (p=0.404) but, in the LD, the mean active stress was much higher in response to the KCl stimulation (p<0.001). Collectively, these results demonstrate that the anisotropic behavior of the vaginal tissue is determined not only by the collagen and smooth muscle fiber organization but also by the innervation. The findings of this study may contribute to the development of more effective treatments for pelvic organ prolapse.
Augmentation of Jet Impingement Heat Transfer on a Grooved Surface Under Wet and Dry Conditions
Alsaiari, Abdulmohsen Omar (Virginia Tech, 2018-11-27)
Array jet impingement cooling experiments were performed on flat and grooved surfaces with the surface at a constant temperature. For the flat surface, power and temperature measurements were performed to obtain convection coefficients under a wide range of operating conditions such as jet speed, orifice to surface stand-of distance, and open area percentage. Cooling performance (CP) was calculated as the ratio between heat transfer and fan power. An empirical model was developed to predict jet impingement heat transfer taking into account the entrainment effects. Experimental results showed that jet impingement can provide high transfer rates with lower rates of cooling cost in comparison to contemporary conventional techniques in the industry. CP values over 279 were measured which are significantly higher than the standard values of 70 to 95 in current technology. The model enhanced prediction accuracy by taking into account the entrainment effects; an effect that is rarely considered in the literature. Experiments on the grooved surfaces were performed at dry and wet surface conditions. Under dry conditions, results showed 10%~55% improvement in heat transfer when compared to the flat surface. Improvement percentage tends to be higher at wider gaps between the array of orifices and the grooved surface. An improvement of 30%~40% was observed when increasing Re either by increasing orifice diameter or jet speed. Similar improvement was observed at higher flow open area percentages. No significant improvement in heat transfer resulted from decreasing the size of the grooves from 3.56mm to 2.54mm. Similarly, no noticeable change in heat transfer resulted from changing the relative position of the jets striking the surface at the top of the grooves to the bottom of the grooves. Deeper grooves with twice the depth gave statistically similar average heat transfer coefficients as shallower grooves. Under wet conditions, a hybrid cooling technique approach was proposed by using air jets impinging on a grooved surface with the grooves containing water. The approached is proposed and evaluated experimentally for its feasibility as an alternative for cooling towers of thermoelectric power plants. Convection heat and mass transfer coefficients were measured experimentally using the heat mass transfer analogy. Results showed that hybrid jet impingement provided high magnitudes of heat flux at low jet speeds and flow rates. High coefficients of performance CP > 3000, and heat fluxes > 8,000W/m2 were observed. Hybrid jet impingement showed 500% improvement as compared to jet impingement on a dry flat surface. CP values of hybrid jet impingement is 600% to 1,500% more as compared to performance of air-cooled condensers and wet cooling towers. Water use for hybrid jet impingement cooling is efficient since evaporation energy is absorbed from the surface directly instead of cooling air to near wet-bulb temperature.
CO2 Minimum Miscibility Pressure and Recovery Mechanisms in Heterogeneous Low Permeability Reservoirs
Zhang, Kaiyi (Virginia Tech, 2019-09-16)
Benefited from the efficiency of hydraulic fracturing and horizon drilling, the production of unconventional oil and gas resources, such as shale gas and tight oil, has grown quickly in 21th century and contributed to the North America oil and gas production. Although the new enhancing oil recover (EOR) technologies and strong demand spike the production of unconventional resources, there are still unknowns in recovery mechanisms and phase behavior in tight rock reservoirs. In such environment, the phase behavior is altered by high capillary pressure owing to the nanoscale pore throats of shale rocks and it may also influence minimum miscibility pressure (MMP), which is an important parameter controlling gas floods for CO2 injection EOR. To investigate this influence, flash calculation is modified with considering capillary pressure and this work implements three different method to calculate MMP: method of characteristics (MOC); multiple mixing cell (MMC); and slim-tube simulation. The results show that CO2 minimum miscibility pressure in nanopore size reservoirs are affected by gas-oil capillary pressure owing to the alternation of key tie lines in displacement. The values of CO2-MMP from three different methods match well. Moreover, in tight rock reservoirs, the heterogeneous pore size distribution, such as the ones seen in fractured reservoirs, may affect the recovery mechanisms and MMP. This work also investigates the effect of pore size heterogeneity on multicomponent multiphase hydrocarbon fluid composition distribution and its subsequent influence on mass transfer through shale nanopores. According to the simulation results, compositional gradient forms in heterogeneous nanopores of tight reservoirs because oil and gas phase compositions depend on the pore size. Considering that permeability is small in tight rocks and shales, we expect that mass transfer within heterogeneous pore size porous media to be diffusion-dominated. Our results imply that there can be a selective matrix-fracture component mass transfer during both primary production and gas injection secondary recovery in fractured shale rocks. Therefore, molecular diffusion should not be neglected from mass transfer equations for simulations of gas injection EOR or primary recovery of heterogeneous shale reservoirs with pore size distribution.
Condensation Frosting: From Ice Bridges to Dry Zones
Nath, Saurabh (Virginia Tech, 2017-09-18)
The most ubiquitous mode of frost formation on substrates is condensation frosting, where dew drops condense on a supercooled surface and subsequently freeze, and has been known since the time of Aristotle. The physics of frost incipience at a microscopic scale has, nevertheless, eluded researchers because of an unjustified ansatz regarding the primary mechanism of condensation frosting. It was widely assumed that during condensation frosting each supercooled droplet in the condensate population freezes in isolation by heterogeneous nucleation at the solid-liquid interface, quite analogous to the mechanism of icing. This assumption has very recently been invalidated with strong experimental evidence which shows that only a single droplet has to freeze by heterogeneous nucleation (typically by edge effects) in order to initiate condensation frosting in a supercooled condensate population. Once a droplet has frozen, it subsequently grows an ice bridge towards its nearest neighboring liquid droplet, freezing it in the process. Thus ensues a chain reaction of ice bridging where the newly frozen droplets grow ice bridges toward their nearest neighbor liquid droplets forming a percolating network of interconnected frozen droplets. Not always are these ice bridges successful in connecting to their adjacent liquid droplets. Sometimes the liquid droplet can completely evaporate before the ice bridges can connect, thus forming a local dry region in the vicinity of the ice bridge. In this work, we first formulate a thermodynamic framework in order to understand the localized vapor pressure gradients that emerge in mixed-mode phase-change systems and govern condensation and frost phenomena. Following this, we study droplet pair interactions between a frozen droplet and a liquid droplet to understand the physics behind the local ice bridge connections. We discuss the emergent scaling laws in ice bridging dynamics, their relative size dependencies, and growth rates. Thereafter, we show how with spatial control of interdroplet distances in a supercooled condensate and temporal control of the first freezing event, we can tune global frost propagation on a substrate and even cause a global failure of all ice bridges to create a dry zone. Subsequently, we perform a systematic study of dry zones and derive a scaling law for dry zones that collapses all of our experimental data spanning a wide parameter space. We then show that almost always the underlying mechanism behind the formation of dry zones around any hygroscopic droplet is inhibition of growth and not inhibition of nucleation. We end with a discussion and preliminary results of our proposed anti-frosting surface that uses ice itself to prevent frost.
Controlling condensation and frost growth with chemical micropatterns
Boreyko, Jonathan B.; Hansen, Ryan R.; Murphy, Kevin R.; Nath, Saurabh; Retterer, Scott T.; Collier, C. Patrick (Springer Nature, 2016-01-22)
In-plane frost growth on chilled hydrophobic surfaces is an inter-droplet phenomenon, where frozen droplets harvest water from neighboring supercooled liquid droplets to grow ice bridges that propagate across the surface in a chain reaction. To date, no surface has been able to passively prevent the in-plane growth of ice bridges across the population of supercooled condensate. Here, we demonstrate that when the separation between adjacent nucleation sites for supercooled condensate is properly controlled with chemical micropatterns prior to freezing, inter-droplet ice bridging can be slowed and even halted entirely. Since the edge-to-edge separation between adjacent supercooled droplets decreases with growth time, deliberately triggering an early freezing event to minimize the size of nascent condensation was also necessary. These findings reveal that inter-droplet frost growth can be passively suppressed by designing surfaces to spatially control nucleation sites and by temporally controlling the onset of freezing events.
Dynamical Phase-Change Phenomena
Ahmadi, Seyedfarzad (Virginia Tech, 2019-06-28)
Matter on earth exists mostly in three different phases of solid, liquid, and gas. With extreme amounts of energy, temperature, or pressure, a matter can be changed between the phases. Six different types of phase-change phenomena are possible: freezing (the substance changes from a liquid to a solid), melting (solid to liquid), condensation (gas to liquid), vaporization (liquid to gas), sublimation (solid to gas), and desublimation (gas to solid). Another form of phase change which will be discussed here is the wetting or dewetting transitions of a superhydrophobic surface, in which the phase residing within the surface structure switches between vapor and liquid. Phase transition phenomena frequently occur in our daily life; examples include: a ``liquid'' to ``solid'' transition when cars decrease their distance at a traffic light, solidification of liquids droplets during winter months, and the dancing of droplets on a non-sticking pan. In this dissertation we will address seven different phase-change problems occurring in nature. We unveil completely new forms of phase-change phenomena that exhibit rich physical behavior. For example, during traffic flow, drivers keep a large distance from the vehicle in front of them to ensure safe driving. When vehicles come to a stop, for example at a red light, drivers voluntarily induce a ``phase transition'' from this ``liquid phase'' to a close-packed ``solid phase''. This phase transition is motivated by the intuition that traveling as far as possible before stopping will minimize the overall travel time. However, we are going to investigate this phase-change process and show that this long standing intuition is wrong. Phase-change of solidification will be discussed for different problems. Moreover, the complex physics of oil as it wicks up sheets of frost and freezing of bubble unveil completely new forms of multiphase flows that exhibit rich physical behavior. Finally, the ``Cassie'' to ``Wenzel'' transition will be investigated for layered nano-textured surfaces. These phenomena will be modeled using thermodynamics and fluid mechanics equations.
Enhanced Portability and Anti-Frosting Functionality of Cryostats for Synchrotron-Based X-ray Imaging
Lowery, Adam Wallace (Virginia Tech, 2022-08-22)
The intensity of light produced from synchrotrons enables X-ray imaging down to the micron and submicron scale. This high degree of resolution is necessary to study metals in hydrated biological samples, where trace (metal) elements are found in the lowest concentration. Water within these aqueous samples will undergo radiolysis and produce various reactive oxygen species, which degrades the quality of information gathered from the sample during X-ray imaging. Studies have shown that the best way to counter the effects of radiolysis and preserve samples in their metabolic state during X-ray imaging is to keep them cryogenically frozen. We have developed affordable cryostats and novel protocol to not only improve cryo-imaging at current third-generation synchrotrons, but also enable cryo-imaging at existing synchrotrons that have limited accessibility. This dissertation will provide a detailed description of the tasks that were accomplished to contribute to the development cryo-imaging. The first task was the fabrication of a portable cryostage. The cryostage's discreet profile and unique design successfully enabled it to be effortlessly adapted into three beamlines across two different DOE facilities and facilitate multiple imaging modalities, i.e., correlative imaging. With the next task, we explored adding an ice frame about the stage to help reduce the accumulation of frost on the surface of a frozen sample that was explored. The addition of the ice frame significantly improved the imaging of frozen samples, nearly doubling the overall image clarity in comparison to when it was absent. The final task saw the application of a cryostream, in place of a cryostage, to provide a cooled convective flux across the sample for 2D and 3D visualization for cryo X-ray imaging.
Experimental and Theoretical Studies of Friction and Adhesion of Elastomeric Materials
Rezaei Mojdehi, Ahmad (Virginia Tech, 2017-10-26)
In this dissertation, four distinct but in some ways related topics, mostly related to experimental and theoretical investigations of friction and adhesion of elastomeric materials, are presented. First, an experimental and theoretical study of the interaction between elastic beams and granular media under compressive loading is performed. Buckling loads of beams with different dimensions and boundary conditions within granular media of different depths and grain sizes are measured, and theoretically approximated using the Ritz energy approach, based on the concept of beam on an elastic foundation. Several nondimensional parameters and a scaling law are derived to characterize different interaction regimes between the beams and granular support. The findings from this work is believed to be helpful for improved understanding of interactions between elastic beams and surrounding elastic foundation with applications to piles, oil pipelines, and robotic needle insertion into soft tissues. Second, the role of axial compliance on the friction of extensible strips is investigated. Significant changes were observed in the static and kinetic friction of strips, when the effective axial compliance was changed. The underlying causes of the changes in the frictional response are explained and quantitatively predicted using an extended shear lag model. We believe that this study provides insights into the effect of axial compliance on the frictional response of materials, paving the way for design and optimization of systems where the static and kinetic friction forces play an important role. Third, the effect of normal force and rate on the kinetic friction of two different elastomers, namely acrylic and silicone-based elastomers is evaluated. A custom-built pendulum test setup was used to perform the friction test in dynamic conditions. Two substantially different responses with respect to the change in normal force were observed and the role of different contributions to the frictional response of viscoelastic materials, i.e. bulk hysteresis friction, adhesion friction, and cohesion friction, are discussed. Different scenarios such as modifying the surface by using graphite powder, reducing test velocity, and also performing drop tests to characterize the surface hysteresis of the elastomers, were considered to further explore the origin of frictional responses of the elastomers. This study could improve insights gained from Dynamic Mechanical Analysis (DMA) data when obtaining and interpreting the effect of normal force on kinetic COF of elastomers with potential applications to tires, shoes, etc. where friction plays an important role. Last, a generalized scaling law, based on the classical fracture mechanics approach, is developed to predict the bond strength of adhesive systems. The proposed scaling law, which depends on the rate of change of bond area with compliance, is in apparent discrepancy with the previously reported scaling relationship that depends on the ratio of area to compliance. This distinction can have a profound impact on the expected bond strength of systems, particularly when failure mechanism changes or the compliance of the load train is increased. Furthermore, the shear lag model is implemented to derive a closed-form relation for the system compliance and the conditions where the two models deviate from each other are discussed and demonstrated. The results obtained from this approach could lead to a better understanding of the relationship between the bond strength and the geometry and mechanical properties of adhesive systems, with applications to different types of adhesive joints such as bio-inspired adhesive, biomedical adhesive tapes, and structural adhesive joints.
Exploiting Interfacial Phenomena to Expel Matter from its Substrate
Mukherjee, Ranit (Virginia Tech, 2021-09-02)
Spontaneous expulsion of various forms and types of matter from their solid substrates has always been an integral part of interfacial physics problems. A thorough understanding of such interactions between a solid surface and different soft materials not only expands our theoretical knowledge, but also has applications in self-cleaning, omniphobic surfaces and phase-change heat transfer. Although there is a renewed interest in the design of robust functional surfaces which can passively remove highly viscous liquids or dew, or retard ice accretion or frost formation, the physics of several dewetting and/or deicing mechanisms are yet to be fully understood. Even though we know how jumping-droplet condensation offers significantly better heat transfer performance than regular dropwise condensation and can liberate foreign particles, fundamental questions on the effect of surface orientation on jumping-droplet condensation or how it helps in large-scale fungal disease epidemic in plants are still unanswered. Thus, we first try to fill the knowledge gap in jumping-droplet condensation by characterizing their orientation-dependence and their role in a large-scale pathogenic rust disease dissemination among wheat. Unfortunately, understanding of such dewetting mechanisms does not necessarily translates to prevention or removal of ice and frost on subzero surfaces. Use of superhydrophobic structures or hygroscopic materials to retard the growth of frost was found to be limiting. Therefore the search for an efficient, inexpensive, and environmentally favorable anti-icing or de-icing mechanism is still underway. Here we give a framework for making a novel de-icing construct by analyzing a peculiar jumping frost phenomena where frost particles spontaneously jump off the surface when a polar liquid is brought above. Lastly, we demonstrate a simple and cost-effective technique to design a slippery liquid-infused surface from low-density hydrocarbon-based polymers, which is able to effectively remove a wide variety of soft materials. The main all-encompassing theme of this dissertation is to enhance our understanding of several dewetting phenomena, which might enable better design and/or mitigation strategies to control the expulsion of various forms of matter from a wide variety of surfaces.
Fog Harps: Elastocapillarity, Droplet Dynamics, and Optimization
Kowalski, Nicholas Gerald (Virginia Tech, 2021-05-18)
Fog harvesting is emerging as a promising means to ease the water shortage crisis in arid regions of the world with ample fog. The current state-of-the-art for fog harvesting is mesh netting, which is accessible yet struggles from a dual constraint: a course mesh lets most microscopic fog droplets pass through it, while a fine mesh clogs. In recent years, fog harps have been gaining attention as a superior alternative to meshes, bypassing these inherent constraints. In this work, we expand upon previous fog harp research with a focus on optimization. First, we analyze wire tangling in a harp due to capillary forces, resulting in a mathematical model that is able to predict when wire tangling will occur. Second, we systematically vary three key parameters of a fog harp (wire material, center-to-center wire pitch, and wire length), arriving at an optimal combination. Finally, we develop a numerical model to describe the dynamics of a fog droplet sliding down a harp wire while coalescing with others littered along it. By applying all knowledge acquired through these studies, the next generation of fog harps will push the performance ceiling of practical fog harvesters higher than ever.
Fog Harvester Having a Vertical Wire Array and Uses Thereof
(United States Patent and Trademark Office, 2022-10-11)
Described herein are fog harvesters having a vertical wire array and systems thereof. The fog harvesters described herein can be used to harvest liquid from the air, such as from fog. The fog harvesters can, in some aspects, have improved performance in one or more aspects as compared to fog harvesters having a mesh design.
Full Field Reconstruction Enhanced With Operational Modal Analysis and Compressed Sensing for General Dynamic Loading
Fu, Gen (Virginia Tech, 2021-06-09)
In most applications, the structure components have to be tested under different loading conditions before being placed in operation. A reliable and low cost measuring technique is desirable. However, most currently employed measuring approaches can only provide the structural response at several discrete locations. The accuracy of the measurements varies with the location and orientation of the sensors. Practically, it is not possible to place sensors at all the critical locations for different excitations. Therefore, an approach that derives the full field response using a limited set of measured data is desirable. In contrast to experimental full field measurement techniques, the expansion approach involves analytically expanding the limited measurements to all the degrees of freedom of the structure. Among all the analytical methods, the modal expansion method is computationally efficient and thus more suitable for real time expansion of measured data. In this method, the full-field response is approximated by the linear combination of mode shapes. In previous studies, the modal expansion method is limited by errors from mode aliasing, inaccuracy of the calculated mode shapes and the noise in measurements. In order to overcome these limitations, the modal expansion method is enhanced by mode selection and error compensation in this study. First, the key parameters used in modal expansion method were analyzed using a cantilever beam model and a method for optimal placement of sensors was developed. A mode selection method and error compensation method based on operation modal analysis and adaptive compressed sensing techniques were then developed to reduce the effects of mode aliasing, mode shape inaccuracy and measurement noise. The developed approach was further tested virtually using a numerical model of rotor 67. The numerical model was created using a two-way coupled fluid structure interaction technique. By developing these methods, the enhanced modal expansion approach can provide full field response for structures under different load conditions. Compared to the traditional modal expansion method, it can expand the data with high noise and under general dynamic loading.
Functional and Morphological Characteristics of Smooth Muscle in the Rat Vagina
Huntington, Alyssa Joan (Virginia Tech, 2021-06-15)
The vagina is an essential organ of the female reproductive system that has been largely understudied in the field of biomechanics. The ability of the vagina to contract gives rise to a set of active mechanical properties that contribute to the complex function of this organ in-vivo. After briefly reviewing experimental studies on the active properties of the vagina, including the differences in contractility with respect to anatomic regions and orientations, neural pathways, life events, pelvic floor disorders, and surgical mesh treatment, we present our novel experimental studies that aim toward filling existing knowledge gaps on vaginal tissue morphology and contractile function of the vagina. First, we quantified the large heterogeneous deformations that the vagina experiences during contractions for the first time. For this study, vaginal specimens were subjected to isometric planar biaxial tests, during which they were induced to contract via KCl at four applied equi-biaxial stretches. The digital image correlation method was used to perform full-field strain analysis during each contraction. The vagina was found to have anisotropic contractile behavior, generating higher forces and experiencing higher magnitude strains along the longitudinal direction (LD) than along the circumferential direction (CD) during contractions. Then, we performed the first detailed quantification of the distribution and alignment of vaginal smooth muscle and nerves throughout the vagina. Toward this goal, vaginas from adult female rats were subjected to a tissue clearing and immunohistochemistry protocol. Tissue clearing increased the transparency of the specimens such that organs could be imaged without sectioning, thus preserving the 3D architecture of the tissue. This analysis revealed a bimodal distribution of muscle alignment angles, with a significantly higher proportion of muscle oriented along the LD than along the CD of the organ. The morphologic and functional properties of the smooth muscle within the healthy vagina need to be fully investigated so that detrimental alterations in vaginal contractility, such as those caused by pelvic floor disorders and current treatment strategies, can be prevented.
How soap bubbles freeze
Ahmadi, S. Farzad; Nath, Saurabh; Kingett, Christian M.; Yue, Pengtao; Boreyko, Jonathan B. (Springer Nature, 2019-06-18)
Droplets or puddles tend to freeze from the propagation of a single freeze front. In contrast, videographers have shown that as soap bubbles freeze, a plethora of growing ice crystals can swirl around in a beautiful effect visually reminiscent of a snow globe. However, the underlying physics of how bubbles freeze has not been studied. Here, we characterize the physics of soap bubbles freezing on an icy substrate and reveal two distinct modes of freezing. The first mode, occurring for isothermally supercooled bubbles, generates a strong Marangoni flow that entrains ice crystals to produce the aforementioned snow globe effect. The second mode occurs when using a cold stage in a warm ambient, resulting in a bottom-up freeze front that eventually halts due to poor conduction along the bubble. Blending experiments, scaling analysis, and numerical methods, the dynamics of the freeze fronts and Marangoni flows are characterized.
Impact and Departure Dynamics of Droplets and Bubbles
Park, Hyunggon (Virginia Tech, 2022-07-11)
Droplets and bubbles are important for understanding natural phenomena such as falling raindrops, airborne disease transmission, and plant respiration systems, and also for engineering contexts such as semiconductor fabrication, nuclear power plants, and electronics cooling. However, still, more understanding is needed of these complex dynamics problems. This dissertation will talk about the droplet impact and bubble departure dynamics that are happening on various surfaces. In Chapters 2 and 3, we will explore how raindrops can transmit plant pathogens. When the raindrop impacts the infected wheat leaf, the micron-sized dry spore can liberate from the surface in two different ways: dry dispersal and wet dispersal. The dry spore can liberate from the surface by the inertia of the drop, after that, the air vortex generated by the drop impact can carry the dry spores above the laminar boundary layer, with the potential for long-distance transport. For the wet dispersal, spore-laden droplets can be generated after raindrop impact, but how these spore-laden droplets can make neighboring plant diseases is still a mystery. We have shown that the splashed droplets can stick to the adjacent healthy leaf depending on the inertia of the impacting droplet, anisotropic leaf orientation, and whether it is treated with fungicide or not. In Chapter 4, We design a micropillar aluminum substrate that preferentially grows frost on top of the pillars. When deposited droplets impact the frost-tipped pillars, the dynamic pressure causes the water to wick within the frost faster than it can impale the gaps between the pillars. Upon freezing, this safely suspends the resulting ice sheet in the air-trapping Cassie state, without any surface coatings required. For the last part (Chapter 5), we investigated the bubble coalescence dynamics that can depart the bubble with a micrometer size. We made the micro-structured surfaces tailored to nucleation sites to enable the coalescence-induced departure of micro-bubbles. A scaling model reveals two different modes of bubble departure following the coalescence-induced depinning: capillary-inertial jumping for micrometric bubbles and a buoyant-inertial departure for millimetric ones. Eventually, this small bubble departure can delay film boiling which can be the barrier to the boiling heat transfer.
Inducing Liquid Evaporation with Hygroscopic Gels
Shukla, Pranav (Virginia Tech, 2019-06-28)
Mammals secrete fluids from the sweat glands known as perspiration which helps in thermoregulation. However, sweat can interfere with vision, comfort, grip, and results in malodor due to bacterial action. To combat the aforementioned issues, antiperspirants are widely used personal hygiene products to stop the sweat by blocking the sweat glands. Typically, aluminum salts present in the antiperspirants dissolve in the sweat and create a temporary plug to cut the flow of sweat. However, there has been a long debate going on the safety concerns of aluminum-based antiperspirants. Although there is no concrete evidence to prove the carcinogenicity of aluminum, various studies have also shown that long exposure to aluminum can lead to breast cancer in women. Hence there is a potential need to find aluminum-free alternatives for antiperspirants. Consumers are also showing an increased demand for more natural cosmetic products. The current study presents a novel aluminum-free the hygroscopic gel which can potentially serve as an antiperspirant. A synthetic sweat duct has been developed to mimic the sweating behavior of humans and to test the synthesized gels. Hygroscopic materials readily absorb and/or adsorb water from a humid environment. The hygroscopic gel can cause long-range evaporation of water from the sweat leading tocrystallization of minerals which can ultimately clog the sweat duct and prevent sweating.
Intelligent Non-Invasive Thermal Energy Flow Rate Sensor for Laminar and Turbulent Pipe Flows
Alanazi, Mohammed Awwad (Virginia Tech, 2022-03-23)
This dissertation describes the development of an intelligent non-invasive thermal energy flow rate sensor for laminar and turbulent pipe flows. Energy flow rate is the thermal energy that is carried by a fluid, for example, in a pipe to heat or cool a space in a building. It can be measured by an energy flow rate sensor which consists of a volume flow rate meter and supply and return fluid temperature sensors to bill the users for their energy usage. A non-invasive, low-cost, and easy to install thermal energy flow rate sensor based on thermal interrogation transient heat flux and temperature measurements has been developed to measure fluid velocity and fluid temperature in pipes. This sensor can be used for different pipe diameters, different pipe materials, and different viscous fluids. The transient measurements are made on the outer surface of a pipe by using a heat flux sensor and a thin-film thermocouple which are covered by a thin-film heater. A one-dimensional transient thermal model is applied before and during activation of the external heater along with a parameter estimation code to provide estimates of the fluid heat transfer coefficient and apparent thermal resistance between the thermocouple and the pipe surface. This dissertation contributes to the sensor's development in three ways. First, a new design is developed by using a single layer of Kapton tape with an adhesive (dielectric material) between the thermocouple foils and the pipe wall to isolate the thermocouple electrically from the pipe surface. This new design gives accurate and reliable estimates of the internal mean fluid temperature without environmental interference. Second, this new sensor design is tested for turbulent pipe flows with two different pipe diameters ( = 25.4 mm and = 12.7 mm) and two different viscous fluids (diesel oil and water). Experiments are completed over a large range of fluid velocity from 0.2 m/s to 5.5 m/s and a range of fluid temperature from 20 ℃ to 50 ℃. The estimated parameters, heat transfer coefficient and apparent thermal resistance, are correlated with the fluid velocity and fluid temperature. This sensor gives a good correlation, repeatability, and sensitivity between the estimated parameters and the fluid velocities with an accurate estimation of the fluid temperatures without environmental interference. Third, this sensor is tested for laminar flow in pipes over a range of fluid velocity from 0.049 m/s to 0.45 m/s and a range of fluid temperature from 20 ℃ to 50 ℃. A new empirical correlation between the estimated parameters and the laminar fluid velocity has been developed. The results show that this sensor gives lower sensitivity and accuracy between the estimated parameters and the fluid velocity and fluid temperature for the laminar flow.

Browsing by Author "Boreyko, Jonathan B."

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