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Bis-(η(2)-ethyl-ene)(η(5)-inden-yl)iridium(I).

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dc.contributor.authorMerola, Joseph S.en
dc.contributor.departmentChemistryen
dc.coverage.spatialUnited Statesen
dc.date.accessioned2016-09-22T15:16:43Zen
dc.date.available2016-09-22T15:16:43Zen
dc.date.issued2013en
dc.description.abstractThe asymmetric unit of the title compound, [Ir(C9H7)(C2H4)2], consists of two independent mol-ecules. The bonding between iridium and the five-membered ring of the indenyl ligand shows the usual asymmetry associated with the typical ring slippage responsible for the enhanced activity of indenyl metal compounds when compared with the analogous cyclo-penta-dienyl metal compound. There are three short Ir-C bonds of 2.210 (3), 2.190 (4) and 2.220 (3) Å and two long Ir-C bonds to the C atoms that are part of the fused six-membered ring of 2.349 (4) and 2.366 (3) Å for one of the independent mol-ecules [2.208 (4), 2.222 (3), 2.197 (4) Å for the short distances and 2.371 (3) and 2.358 (3) Å for the long distances in the second mol-ecule]. This results in both indenyl ligands being slightly kinked, with dihedral angles of 6.8 (4)° and 6.5 (4)°.en
dc.description.versionPublished versionen
dc.format.extentm547 - ? page(s)en
dc.format.mimetypeapplication/pdfen
dc.identifier.doihttps://doi.org/10.1107/S1600536813025300en
dc.identifier.eissn1600-5368en
dc.identifier.issuePt 10en
dc.identifier.urihttp://hdl.handle.net/10919/73016en
dc.identifier.volume69en
dc.languageengen
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/24098177en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.titleBis-(η(2)-ethyl-ene)(η(5)-inden-yl)iridium(I).en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen

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