Crystal structure of di-μ-chlorido-bis-[di-chlorido-bis-(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chlorido-iridium(III) dinuclear complex with methanol ligands

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dc.contributorVirginia Tech. Department of Chemistryen
dc.contributor.authorMerola, Joseph S.en
dc.contributor.authorSlebodnick, Carlaen
dc.contributor.authorHouser, Christopheren
dc.contributor.departmentChemistryen
dc.coverage.spatialEnglanden
dc.date.accessioned2016-09-22T19:57:09Zen
dc.date.available2016-09-22T19:57:09Zen
dc.date.issued2015-05-01en
dc.description.abstractThe reaction between IrCl3·xH2O in methanol led to the formation of small amounts of the title compound, [Ir2Cl6(CH3OH)4]·2H2O, which consists of two IrCl4O2 octa-hedra sharing an edge via chloride bridges. The mol-ecule lies across an inversion center. Each octa-hedron can be envisioned as being comprised of four chloride ligands in the equatorial plane with methanol ligands in the axial positions. A lattice water mol-ecule is strongly hydrogen-bonded to the coordinating methanol ligands and weak inter-actions with coordinating chloride ligands lead to the formation of a three-dimensional network. This is a surprising structure given that, while many reactions of iridium chloride hydrate are carried out in alcoholic solvents, especially methanol and ethanol, this is the first structure of a chloridoiridium compound with only methanol ligands.en
dc.description.sponsorshipVirginia Tech. Open Access Subvention Funden
dc.description.versionPublished versionen
dc.format.extent528 - 530 page(s)en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationMerola, J. S., Slebodnick, C., & Houser, C. (2015). Crystal structure of di-μ-chlorido-bis­­[di­chlorido­bis­­(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chlorido­iridium(III) dinuclear complex with methanol ligand. Acta Crystallographica Section E, 71(5), 528-530. doi:doi:10.1107/S205698901500667en
dc.identifier.doihttps://doi.org/10.1107/S2056989015006672en
dc.identifier.eissn2056-9890en
dc.identifier.issuePt 5en
dc.identifier.issue5en
dc.identifier.sourceurlhttp://scripts.iucr.org/cgi-bin/paper?S2056989015006672en
dc.identifier.urihttp://hdl.handle.net/10919/73028en
dc.identifier.volume71en
dc.language.isoenen
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/25995872en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectchlorido bridgeen
dc.subjectcrystal structureen
dc.subjecthydrogen bondingen
dc.subjectiridiumen
dc.subjectmethanol liganden
dc.titleCrystal structure of di-μ-chlorido-bis-[di-chlorido-bis-(methanol-κO)iridium(III)] dihydrate: a surprisingly simple chlorido-iridium(III) dinuclear complex with methanol ligandsen
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
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pubs.organisational-group/Virginia Tech/Science/Chemistryen
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