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Crystal structure of chlorido-(η(2)-phenyl iso-thio-cyanate-κ(2) C,S)-mer-tris-(tri-methyl-phosphane-κP)iridium(I).

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dc.contributorVirginia Tech. Department of Chemistryen
dc.contributor.authorMerola, Joseph S.en
dc.contributor.authorGrieb, Aarthur W.en
dc.contributor.departmentChemistryen
dc.coverage.spatialUnited Statesen
dc.date.accessioned2016-09-22T19:55:42Zen
dc.date.available2016-09-22T19:55:42Zen
dc.date.issued2014-11-01en
dc.description.abstractThe molecule of the title compound, [IrCl(C7H5NS)(C3H9P)3], is a distorted octa-hedral iridium complex with three PMe3 ligands arranged in a meridional geometry, a chloride ion cis to all three PMe3 groups and the phenyl iso-thio-cyanate ligand bonded in an η(2)-fashion through the C and S atoms. The C atom is trans to the chloride ion and the S atom is responsible for a significant deviation from an ideal octa-hedral geometry. The geometric parameters for the metal-complexing phenyl isothiocyanate group are compared with other metal-complexed phenyl iso-thio-cyanates, as well as with examples of uncomplexed aryl iso-thio-cyanates.en
dc.description.sponsorshipVirginia Tech. Open Access Subvention Funden
dc.description.versionPublished versionen
dc.format.extent9 pagesen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationMerola, J. S., A. W. Grieb (2014). Crystal structure of chlorido­(η2-phenyl iso­thio­cyanate-κ2C,S)-mer-tris­­(tri­methyl­phosphane-κP)iridium(I). Acta Crystallographica Section E, 70(11), 352-354. doi:doi:10.1107/S160053681402162Xen
dc.identifier.doihttps://doi.org/10.1107/S160053681402162Xen
dc.identifier.eissn1600-5368en
dc.identifier.issuePt 11en
dc.identifier.sourceurlhttp://scripts.iucr.org/cgi-bin/paper?S160053681402162Xen
dc.identifier.urihttp://hdl.handle.net/10919/73026en
dc.identifier.volume70en
dc.languageengen
dc.publisherInternational Union of Crystallographyen
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/25484743en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectcrystal structureen
dc.subjectiridium complexen
dc.subjectphenyl iso­thio­cyanateen
dc.titleCrystal structure of chlorido-(η(2)-phenyl iso-thio-cyanate-κ(2) C,S)-mer-tris-(tri-methyl-phosphane-κP)iridium(I).en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen

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