A New Family of High Tc Molecule-Based Magnetic Networks: V[x-ClnPTCE]2·yCH2Cl2 (PTCE = Phenyltricyanoethylene)

dc.contributor.authorTatum, David S.en
dc.contributor.authorZadrozny, Joseph M.en
dc.contributor.authorYee, Gordon T.en
dc.contributor.departmentChemistryen
dc.date.accessioned2019-08-09T12:24:27Zen
dc.date.available2019-08-09T12:24:27Zen
dc.date.issued2019-08-01en
dc.date.updated2019-08-09T08:01:36Zen
dc.description.abstractUsing the structural and electronic tunability of molecules to control magnetism is a central challenge of inorganic chemistry. Herein, a ten-member family of the high-ordering temperature (<i>T</i><sub>c</sub>) molecule-based magnetic coordination networks of the form V[<i>x</i>-Cl<sub>n</sub>PTCE]<sub>2</sub>&middot;<i>y</i>CH<sub>2</sub>Cl<sub>2</sub> (PTCE = phenyltricyanoethylene, <i>y</i> &lt; 0.5) were synthesized and characterized, where <i>x</i> is (are) the position(s) and n is the number of chlorine substitutions on the phenyl ring. These chlorophenyltricyanoethelenes are tunable analogs of the more commonly investigated tetracyanoethylene (TCNE). Varying the number and position of chlorine substitution around the phenyl ring engendered a family of network solids with significantly different magnetic ordering temperatures ranging from 146 to 285 K. The <i>T<sub>c</sub></i>s of these ferrimagnets were rationalized with the aid of cyclic voltammetry and Density Functional Theory (DFT) calculations.en
dc.description.versionPublished versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.citationTatum, D.S.; Zadrozny, J.M.; Yee, G.T. A New Family of High Tc Molecule-Based Magnetic Networks: V[x-ClnPTCE]2·yCH2Cl2 (PTCE = Phenyltricyanoethylene). Magnetochemistry 2019, 5, 44.en
dc.identifier.doihttps://doi.org/10.3390/magnetochemistry5030044en
dc.identifier.urihttp://hdl.handle.net/10919/93012en
dc.language.isoenen
dc.publisherMDPIen
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectmolecule-based ferrimagnetismen
dc.titleA New Family of High Tc Molecule-Based Magnetic Networks: V[x-ClnPTCE]2·yCH2Cl2 (PTCE = Phenyltricyanoethylene)en
dc.title.serialMagnetochemistryen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten

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