Tri-methyl-phospho-nium trans-tetra-chlorido-bis-(tri-methyl-phosphane-κP)iridate(III)

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dc.contributor.authorBerg, M. A.en
dc.contributor.authorDavidson, J.en
dc.contributor.authorMerola, Joseph S.en
dc.contributor.departmentChemistryen
dc.date.accessioned2016-09-22T19:55:00Zen
dc.date.available2016-09-22T19:55:00Zen
dc.date.issued2014-03-01en
dc.description.abstractThe title compound, [HP(CH3)3][IrCl4{(H3C)3P}2], consists of a tri-methyl-phospho-nium cation and a tetra-chlorido-bis-(tri-methyl-phosphane)iridate(III) anion. The anion has an octa-hedral arrangement of ligands, with the tri-methyl-phosphane groups occupying trans positions. The Ir(III) atom sits on an inversion center with one P(CH3)3 ligand and two chloride ligands in the asymmetric unit. The tri-methyl-phospho-nium cation is disordered about a twofold rotation axis. The title compound is the first structurally characterized tetra-chlorido-bis-(phosphane)iridate complex.en
dc.description.versionPublished versionen
dc.format.mimetypeapplication/pdfen
dc.identifier.doihttps://doi.org/10.1107/S160053681400350Xen
dc.identifier.eissn1600-5368en
dc.identifier.issuePt 3en
dc.identifier.urihttp://hdl.handle.net/10919/73025en
dc.identifier.volume70en
dc.language.isoenen
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/24764937en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.titleTri-methyl-phospho-nium trans-tetra-chlorido-bis-(tri-methyl-phosphane-κP)iridate(III)en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen

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