Crystal structure of the tetra-meth-yl(pheneth-yl)cyclo-penta-dienylmolybdenumtricarbonyl dimer.

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dc.contributor.authorBrown, Loren C.en
dc.contributor.authorMarron, Dannyen
dc.contributor.authorSmith, Caseyen
dc.contributor.authorMerola, Joseph S.en
dc.contributor.departmentChemistryen
dc.date.accessioned2019-02-07T16:41:27Zen
dc.date.available2019-02-07T16:41:27Zen
dc.date.issued2018-07en
dc.date.updated2019-02-07T16:41:23Zen
dc.description.abstractThe structure of the dimer bis-{tricarbon-yl[η5-tetra-meth-yl(pheneth-yl)cyclo-penta-dien-yl]molybdenum}(Mo-Mo), [Mo2(C17H21)2(CO)6], at 102 K has triclinic (P ) symmetry. The reaction between tetra-meth-yl(pheneth-yl)cyclo-penta-diene and molybdenum hexa-carbonyl in refluxing xylenes for 18 h led to a 56% yield of the dimer as a red solid. The asymmetric unit of the structure is the tetra-meth-yl(pheneth-yl)cyclo-penta-dienylmolybdenumtricarbonyl moiety and the entire dimeric mol-ecule is generated by inversion symmetry. The Mo-Mo bond length is 3.2773 (3) Å, a value slightly above the mean value for all [CpMo(CO)3]2 compounds listed in the CSD and slightly below the mean for [Cp*Mo(CO)3]2 complexes.en
dc.description.notesjournal: Acta Crystallographica Section E: Crystallographic Communications content_type: research communications article_metrics: Available peer_reviewed: Yes review_process: Single blind received: 13 June 2018 accepted: 17 June 2018 published_online: 26 June 2018 supplementary_materials: This article has supporting information copyright: © 2018 Brown license: Creative Commons Attribution (CC-BY)en
dc.description.versionPublished versionen
dc.format.extentPages 1017-1020en
dc.format.mediumElectronic-eCollectionen
dc.identifier.doihttps://doi.org/10.1107/S2056989018008885en
dc.identifier.eissn2056-9890en
dc.identifier.issn2056-9890en
dc.identifier.issuePt 7en
dc.identifier.orcidMerola, Joseph [0000-0002-1743-1777]en
dc.identifier.otherPMC6038615en
dc.identifier.otherpj2053 (PII)en
dc.identifier.pmid30002907en
dc.identifier.urihttp://hdl.handle.net/10919/87527en
dc.identifier.volume74en
dc.languageengen
dc.publisherInternational Union of Crystallographyen
dc.relation.urihttps://www.ncbi.nlm.nih.gov/pubmed/30002907en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectcarbonyl complexen
dc.subjectcrystal structureen
dc.subjectcyclo­penta­dienyl liganden
dc.subjectmetal dimeren
dc.subjectmolybdenumen
dc.titleCrystal structure of the tetra-meth-yl(pheneth-yl)cyclo-penta-dienylmolybdenumtricarbonyl dimer.en
dc.title.serialActa crystallographica. Section E, Crystallographic communicationsen
dc.typeArticle - Refereeden
dc.type.otherresearch-articleen
dc.type.otherJournal Articleen
dcterms.dateAccepted2018-06-17en
pubs.organisational-group/Virginia Tech/Scienceen
pubs.organisational-group/Virginia Techen
pubs.organisational-group/Virginia Tech/Faculty of Health Sciencesen
pubs.organisational-group/Virginia Tech/All T&R Facultyen
pubs.organisational-group/Virginia Tech/Science/Chemistryen
pubs.organisational-group/Virginia Tech/Science/COS T&R Facultyen
pubs.organisational-group/Virginia Tech/University Research Institutes/Fralin Life Sciences/Fralin Affiliated Facultyen
pubs.organisational-group/Virginia Tech/University Research Institutes/Fralin Life Sciencesen
pubs.organisational-group/Virginia Tech/University Research Institutesen

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