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dc.contributor.authorMerola, Joseph S.en_US
dc.contributor.authorFranks, Marion A.en_US
dc.coverage.spatialEnglanden_US
dc.date.accessioned2016-09-21T16:16:30Z
dc.date.available2016-09-21T16:16:30Z
dc.date.issued2015-02-01en_US
dc.identifier.citationMerola, J. S., & Franks, M. A. (2015). Crystal structures of fac-tri­chlorido­tris­­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs. Acta Crystallographica Section E, 71(2), 226-230. doi:doi:10.1107/S205698901500151
dc.identifier.urihttp://hdl.handle.net/10919/72970
dc.description.abstractThe crystal structures of two solvates of fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3]·0.5CH3OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013). Polyhedron, 54, 67-73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.en_US
dc.description.sponsorshipACS–PRF
dc.description.sponsorship23961-C1
dc.description.sponsorshipNational Science Foundation
dc.description.sponsorshipCHE-902244
dc.description.sponsorshipVirginia Tech. Open Access Subvention Fund
dc.format.extent226 - 230 page(s)en_US
dc.format.mimetypeapplication/pdfen_US
dc.languageengen_US
dc.publisherInternational Union of Crystallography
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/25878826en_US
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectcrystal structureen_US
dc.subjectiridiumen_US
dc.subjectisotypismen_US
dc.subjectphosphane ligandsen_US
dc.subjectrhodiumen_US
dc.titleCrystal structures of fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) monohydrate and fac-tri-chlorido-tris-(tri-methyl-phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs.en_US
dc.typeArticle - Refereeden_US
dc.contributor.departmentChemistryen_US
dc.description.notesPublished online (Publication status)en_US
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen_US
dc.identifier.doihttps://doi.org/10.1107/S2056989015001516
dc.identifier.volume71en_US
dc.identifier.issuePt 2en_US
dc.type.dcmitypeTexten_US
dc.identifier.sourceurlhttp://journals.iucr.org/e/issues/2015/02/00/pk2543/index.html
dc.identifier.eissn2056-9890en_US
pubs.organisational-group/Virginia Tech
pubs.organisational-group/Virginia Tech/All T&R Faculty
pubs.organisational-group/Virginia Tech/Faculty of Health Sciences
pubs.organisational-group/Virginia Tech/Science
pubs.organisational-group/Virginia Tech/Science/Chemistry
pubs.organisational-group/Virginia Tech/Science/COS T&R Faculty


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