Serendipitous preparation of fac-(aceto-nitrile-κN)tri-chlorido-[(1,2,5,6-η)-cyclo-octa-1,5-diene]iridium(III)

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dc.contributor.authorMorris, David M.en
dc.contributor.authorMerola, Joseph S.en
dc.contributor.departmentChemistryen
dc.coverage.spatialEnglanden
dc.date.accessioned2016-09-22T19:56:51Zen
dc.date.available2016-09-22T19:56:51Zen
dc.date.issued2015-04-01en
dc.description.abstractA reaction between [(COD)IrCl]2 (COD is cyclo-octa-1,5-diene), HCl and indene failed to provide the hoped for chlorido-indenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an octa-hedral complex of iridium(III) with a chelating cyclo-octa-1,5-diene ligand, three chloride ligands in a fac arrangement, and one aceto-nitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.en
dc.description.sponsorshipVirginia Tech. Open Access Subvention Funden
dc.description.versionPublished versionen
dc.format.extent371 - 373 page(s)en
dc.format.mimetypeapplication/pdfen
dc.identifier.citationMorris, D. M., & Merola, J. S. (2015). Serendipitous preparation of fac-(aceto­nitrile-κN)tri­chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene]iridium(III). Acta Crystallographica Section E, 71(4), 371-373. doi:doi:10.1107/S205698901500485en
dc.identifier.doihttps://doi.org/10.1107/S2056989015004855en
dc.identifier.eissn2056-9890en
dc.identifier.issuePt 4en
dc.identifier.sourceurlhttp://journals.iucr.org/e/issues/2015/04/00/pk2547/index.htmlen
dc.identifier.urihttp://hdl.handle.net/10919/73027en
dc.identifier.volume71en
dc.language.isoenen
dc.publisherInternational Union of Crystallographyen
dc.relation.urihttp://www.ncbi.nlm.nih.gov/pubmed/26029393en
dc.rightsCreative Commons Attribution 4.0 Internationalen
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/en
dc.subjectaceto­nitrileen
dc.subjectcrystal structureen
dc.subjectcyclo­octa­dieneen
dc.subjectiridiumen
dc.titleSerendipitous preparation of fac-(aceto-nitrile-κN)tri-chlorido-[(1,2,5,6-η)-cyclo-octa-1,5-diene]iridium(III)en
dc.title.serialActa Crystallographica Section E: Structure Reports Onlineen
dc.typeArticle - Refereeden
dc.type.dcmitypeTexten
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pubs.organisational-group/Virginia Tech/Science/Chemistryen
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